The Chemistry of Hat Manufacturing: Lectures Delivered Before the Hat Manufacturers' AssociationSmith, Watson
Science
The Chemistry of Hat Manufacturing: Lectures Delivered Before the Hat Manufacturers' Association
Smith, Watson
Hats
So far everything in the treatment of the wool has been perfectly
favourable for the subsequent operations of the felt-hat dyer, but now I
come to a process which I consider I should be perfectly unwarranted in
passing over before proceeding to the dyeing processes. In fact, were it
not for this "proofing process" (see Lecture VII.) the dyeing of felt
hats would be as simple and easy of attainment as the ordinary dyeing of
whole-wool fabrics. Instead of this, however, I consider the hat
manufacturer, as regards his dyeing processes as applied to the stiffer
classes of felt hats, has difficulties to contend with fully comparable
with those which present themselves to the dyer of mixed cotton and
woollen or Bradford goods. You have heard that the purpose of the
wool-scourer is to remove the dirt, grease, and so-called yolk, filling
the pores and varnishing the fibres. Now the effect of the work of the
felt or felt-hat proofer is to undo nearly all this for the sake of
rendering the felt waterproof and stiff. The material used, also, is
even more impervious and resisting to the action of aqueous solutions of
dyes and mordants than the raw wool would be. In short, it is impossible
to mordant and to dye shellac by any process that will dye wool. To give
you an idea of what it is necessary to do in order to colour or dye
shellac, take the case of coloured sealing-wax, which is mainly composed
of shellac, four parts, and Venice turpentine, one part. To make red
sealing-wax this mixture is melted, and three parts of vermilion, an
insoluble metallic pigment, are stirred in. If black sealing-wax is
required, lamp-black or ivory-black is stirred in. The fused material is
then cast in moulds, from which the sticks are removed on cooling. That
is how shellac may be coloured as sealing-wax, but it is a totally
different method from that by which wool is dyed. The difficulty then is
this--in proofing, your hat-forms are rendered impervious to the dye
solutions of your dye-baths, all except a thin superficial layer, which
then has to be rubbed down, polished, and finished. Thus in a short
time, since the bulk of that superficially dyed wool or fur on the top
of every hat is but small, and has been much reduced by polishing and
rubbing, you soon hear of an appearance of bareness--I was going to say
threadbareness--making itself manifest. This is simply because the
colour or dye only penetrates a very little way down into the substance
of the felt, until, in fact, it meets the proofing, which, being as it
ought to be, a waterproofing, cannot be dyed. It cannot be dyed either
by English or German methods; neither logwood black nor coal-tar blacks
can make any really good impression on it. Cases have often been
described to me illustrating the difficulty in preventing hats which
have been dyed black with logwood, and which are at first a handsome
deep black, becoming rather too soon of a rusty or brownish shade. Now
Public-domain text, read in full here on John Shaqi.
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