The Chemistry of Hat Manufacturing: Lectures Delivered Before the Hat Manufacturers' AssociationSmith, Watson
Science
The Chemistry of Hat Manufacturing: Lectures Delivered Before the Hat Manufacturers' Association
Smith, Watson
Hats
my belief is that two causes may be found for this deterioration. One is
the unscientific method adopted in many works of using the same bath
practically for about a month together without complete renewal. During
this time a large quantity of a muddy precipitate accumulates, rich in
hydrated oxide of iron or basic iron salts of an insoluble kind. This
mud amounts to no less than 25 per cent. of the weight of the copperas
used. From time to time carbonate of ammonia is added to the bath, as it
is said to throw up "dirt." The stuff or "dirt," chiefly an ochre-like
mass stained black with the dye, and rich in iron and carbonate of iron,
is skimmed off, and fresh verdigris and copperas added with another lot
of hat-forms. No doubt on adding fresh copperas further precipitation of
iron will take place, and so this ochre-like precipitate will
accumulate, and will eventually come upon the hats like a kind of thin
black mud. Now the effect of this will be that the dyestuff, partly in
the fibre as a proper dye, and not a little on the fibre as if
"smudged" on or painted on, will, on exposure to the weather, moisture,
air, and so on, gradually oxidise, the great preponderance of iron on
the fibre changing to a kind of iron-rust, corroding the fibres in the
process, and thus at once accounting for the change to the ugly brownish
shade, and to the rubbing off and rapid wearing away of the already too
thin superficial coating of dyed felt fibre. In the final spells of
dyeing in the dye-beck already referred to, tolerably thick with black
precipitate or mud, the application of black to the hat-forms begins, I
fear, to assume at length a too close analogy to another blacking
process closely associated with a pair of brushes and the time-honoured
name of Day & Martin. With that logwood black fibre, anyone could argue
as to a considerable proportion of the dye rubbing, wearing, or washing
off. Thus, then, we have the second cause of the deterioration of the
black, for the colour could not go into the fibre, and so it was chiefly
laid or plastered on. You can also see that a logwood black hat dyer may
well make the boast, and with considerable appearance of truth, that for
the purposes of the English hat manufacturers, logwood black dyeing is
the most appropriate, _i.e._ for the dyeing of highly proofed and stiff
goods, but as to the permanent character of the black colour on those
stiff hats, there you have quite another question. I firmly believe that
in order to get the best results either with logwood black or "aniline
blacks," it is absolutely necessary to have in possession a more
scientific and manageable process of proofing. Such a process is that
invented by F.W. Cheetham (see Lecture VII. p. 66).
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