The Chemistry of Plant LifeThatcher, Roscoe Wilfred
Science
The Chemistry of Plant Life
Thatcher, Roscoe Wilfred
Botanical chemistry
Air-dried starch contains from 15 to 20 per cent of water; but this can be
completely removed, without altering the starch in any way, by heating for
some time at 100° C.
The starch granules from different sources vary considerably in size and
shape, and can generally be identified by observation under the microscope.
The most characteristic reaction of starch is the blue color which it gives
with iodine. The reaction is most marked with starch paste or soluble
starch, but even dry starch granules are colored blue when moistened with a
solution of iodine in water containing potassium iodide, or with tincture
of iodine.
When hydrolyzed, either by boiling with dilute acids or under the influence
of enzymes, starch undergoes a series of decompositions, yielding first
dextrins, then maltose, and finally glucose. These transformations can be
traced by the iodine color reaction, as starch will show its characteristic
blue, dextrins purple or rose-red, and maltose and glucose no color with
iodine.
=Dextrins= may occur in plants as transition products in the transformation
of starch into sugars, or _vice versa_. Most commonly, however, they are
artificial products resulting from the partial hydrolysis of starch in the
laboratory or factory. They are amorphous substances, which are readily
soluble in water, forming sticky solutions which are often used as
adhesives ("library paste" is a common example of a very concentrated
preparation of this kind). They are precipitated from solution by alcohol,
but not by lead subacetate (distinction from starch). They are strongly
dextrorotatory (specific rotatory power +192° to +196°); are not fermented
by yeast alone, but readily undergo hydrolysis to glucose which does
ferment. There are several different modifications, or forms, of dextrins,
depending upon the extent to which the simplification of the starch
molecule by hydrolysis is carried. Three fairly definite forms are
generally recognized, as follows: _amylo-dextrin_, or soluble starch,
slightly soluble in cold water, readily so in hot water, giving a blue
color with iodine; _erythro-dextrin_ easily soluble in water, neutral
taste, red color with iodine; and _achroo-dextrin_, easily soluble in
water, sweetish taste, no color with iodine.
Commercial dextrin, which is much used in the preparation of mucilages and
adhesive pastes, is prepared by heating dry starch to about 250° C. It is
composed chiefly of achroo-dextrin, mixed with varying quantities of
erythro-dextrin and glucose.
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