The Chemistry of Plant LifeThatcher, Roscoe Wilfred
Science
The Chemistry of Plant Life
Thatcher, Roscoe Wilfred
Botanical chemistry
=Glycogen=, or "animal starch," is one of the most widely distributed
reserve foods of the animal body; in fact, it is the only known form of
carbohydrate-reserve in animal tissues. But it is present only rarely in
plants. It occurs in certain fungi, particularly in yeasts. In the animal
body, glycogen is found in all growing cells; also in the muscles and
blood; but most largely in the liver, where it is stored in large
quantities. The glycogen found in yeasts is identical with that found in
animal tissues. The quantity of glycogen in a yeast cell increases rapidly
as the yeast grows during the fermentation process.
Glycogen is a white, amorphous compound, readily soluble in hot water,
forming an opalescent solution similar in appearance to the solutions of
soluble starch. It is strongly dextrorotatory (specific rotatory power
+190°), is colored brown by iodine, and is hydrolyzed to dextrin and
maltose, and finally to glucose.
=Lichenin=, =para dextran=, and =para isodextran= are dextrosans which have
been isolated from various lower plants. They all yield glucose when
completely hydrolyzed. They resemble starch in chemical properties, but
differ from it in physical form, etc.
(B) LEVULOSANS
=Inulin= replaces starch as the reserve food carbohydrate in a considerable
number of natural orders of plants, particularly in the Compositae. It is
the carbohydrate of the tubers of the dahlia and artichoke and of the
fleshy roots of chicory. It is often found associated with starch in
monocotyledonous plants, such as many species of _Iris_, _Hyacinthus_, and
_Muscari_. Among the monocotyledons, starch seems to be the characteristic
carbohydrate reserve of aquatic, or moisture-loving, species, while inulin
is more common among those which prefer dry situations.
Inulin may be prepared from the tubers of dahlias or artichokes, by boiling
the crushed tubers with water containing a little chalk (to precipitate
mineral salts, albumins, etc.) filtering and cooling the filtrate
practically to the freezing point, which precipitates the inulin.
Inulin is a white, tasteless, semi-crystalline powder, which is soluble in
hot water, from which it may be precipitated by alcohol or by freezing. It
forms no paste like that of starch or dextrin, and gives no color with
iodine. It is levorotatory, and when hydrolyzed by acids or by the enzyme
_inulinase_ yields fructose; in fact, inulin bears the same relation to
fructose that starch does to glucose.
=Graminin, irisin, phlein, sinistrin, and triticin= are all inulin-like
polysaccharides, which have been found in the plants after which they are
named. Their solutions are, as a rule, sticky or gummy in consistency,
which suggests that these compounds bear the same relation to inulin that
dextrins do to starch.
(C) MANNOSANS, OR MANNANS
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