The chemistry, properties and tests of precious stonesMastin, John
Science
The chemistry, properties and tests of precious stones
Mastin, John
Precious stones
On certain stones being extracted and placed in other liquids of lighter
or denser specific gravity, as the case may be, their proper
classification may easily be arrived at, and if the results are checked
by actual weight, in a specific gravity balance, they will be found to
be fairly accurate. The solution commonly used for the heaviest stones
is a mixture of nitrate of thallium and nitrate of silver. This double
nitrate has a specific gravity of 4.7963, therefore such a stone as
zircon, which is the heaviest known, will float in it. For use, the
mixture should be slightly warmed till it runs thin and clear; this is
necessary, because at 60 deg. (taking this as ordinary atmospheric
temperature) it is a stiff mass. A lighter liquid is a mixture of iodide
of mercury in iodide of potassium, but this is such an extremely
corrosive and dangerous mixture, that the more common solution is one
in which methylene iodide is saturated with a mixture of iodoform until
it shows a specific gravity of 3.601; and by using the methylene iodide
alone, in its pure state, it having a specific gravity of 3.2981, the
stones to that weight can be isolated, and by diluting this with
benzole, its weight can be brought down to that of the benzole itself,
as in the case of Sonstadt's solution. This solution, in full standard
strength, has a specific gravity of 3.1789, but may be weakened by the
addition of distilled water in varying proportions till the weight
becomes almost that of water.
Knowing the specific gravity of all stones, and dividing them into six
groups, by taking a series of standard solutions selected from one or
other of the above, and of known specific gravity, we can judge with
accuracy if any stone is what it is supposed to be, and classify it
correctly by its mere floating or sinking when placed in these liquids.
Beginning then with the pure double nitrate of silver and thallium, this
will isolate the stones of less specific gravity than 4.7963, and taking
the lighter solutions and standardising them, we may get seven solutions
which will isolate the stones as follows:--
A {shows the stones which have} 4.7963
{a specific gravity over}
B " " " 3.70 and under 4.7963
C " " " 3.50 " 3.70
D " " " 3.00 " 3.50
E " " " 2.50 " 3.00
F " " " 2.00 " 2.50
G " " -- -- under 2.00
Therefore each liquid will isolate the stones in its own group by
compelling them to float on its surface; commencing with the heaviest
and giving to the groups the same letters as the liquids, it is seen
that--
_Group_ A.--Isolates gems with a specific gravity of 4.7963 and over
4.70; in this group is placed zircon, with a specific gravity of from
4.70 to 4.88.
_Group_ B.--Stones whose specific gravity lies between 3.70 and under
4.7963.
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