The chemistry, properties and tests of precious stonesMastin, John
Science
The chemistry, properties and tests of precious stones
Mastin, John
Precious stones
The moisture falling in dew and rain becomes acidulated with carbonic
acid, CO_{2} (carbon dioxide), from the combustion and decay of organic
matter, vegetation, and other sources, and this moisture is capable of
dissolving certain calcareous substances, which it takes deep into the
earth, till the time comes when it enters perhaps a division-plane in
some rock, or some such cavity, and is unable to get away. The hollow
becomes filled with water, which is slowly more and more charged with
the salts brought down, till saturated; then super-saturated, so that
the salts become precipitated, or perhaps crystallised out, maybe by the
presence of more or other salts, or by a change in temperature. These
crystals then become packed hard by further supplies and pressure, till
eventually, after the lapse of ages, a natural gem is found, _exactly
filling_ the cavity, and is a precious find in many cases.
If now we try to find its analogy in chemistry, and for a moment
consider the curious behaviour of some well-known salts, under different
conditions of temperature, what is taking place underground ceases to be
mysterious and becomes readily intelligible.
Perhaps the best salt for the purpose, and one easy to obtain for
experiment, is the sulphate of sodium--known also as Glauber's Salt.
It is in large, colourless prisms, which may soon be dissolved in about
three parts of water, so long as the water does not exceed 60 deg. F., and
at this temperature a super-saturated solution may easily be made. But
if the water is heated the salt then becomes more and more insoluble as
the temperature increases, till it is completely insoluble.
If a super-saturated solution of this Glauber's Salt is made in a glass,
at ordinary atmospheric temperature, and into this cold solution,
without heating, is dropped a small crystal of the same salt, there will
be caused a rise in temperature, and the whole will then crystallise out
quite suddenly; the water will be absorbed, and the whole will solidify
into a mass which exactly fits the inner contour of the vessel.
We have now formed what _might_ be a precious stone, and no doubt would
be, if continuous pressure could be applied to it for perhaps a few
thousand years; at any rate, the formation of a natural jewel is not
greatly different, and after being subjected for a period, extending to
ages, to the washings of moisture, the contact of its containing bed
(its later matrix), the action of the changes in the temperature of the
earth in its vicinity, it emerges by volcanic eruption, earthquake,
landslip and the like, or is discovered as a rare and valuable specimen
of some simple compound of earth-crust and water, as simple as Glauber's
Salt, or as the pure crystallized carbon.
Public-domain text, read in full here on John Shaqi.
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