The Daguerreian Journal, Vol. I, No. 8, March 1, 1851Various
Science
The Daguerreian Journal, Vol. I, No. 8, March 1, 1851
Various
Daguerreotype; Photography -- Periodicals
Process.--When common salt is prepared from sea-water by evaporation and
crystallization, a liquid remains which goes under the name of _bittern_.
This liquid on passing chlorine through it, is tinged with a deep yellow
color. The liquid is now distilled, and the vapor passed over a substance,
(muriate of lime), which has a powerful attraction for water. A small
quantity of bromine is thus obtained.--Another method is to agitate the
chlorinated bittern with a portion of sulphuric ether. The ether dissolves
the bromine, from which it receives a beautiful red tint, and on standing,
rises to the surface. Agitate this solution with caustic potash, and the
bromide of potassium and bromate of potassa will be formed. Evaporate the
liquor and the bromide of potassium will be left from which bromine may be
distilled.
Properties.--At common temperatures, it rapidly volatilizes, giving red
vapors of a most disagreeable smell. Its color, when held between the
eye and the light is a deep hyacinth red. Like oxygen, chlorine, and
iodine, it is a non-conductor of electricity, and a negative electric. It
boils at 116·5°, and congeals at 40 Fahr. into a brittle solid. It is a
powerful poison; even its vapor would no doubt prove fatal, if inhaled in
large quantities. A single drop placed in the beak of a bird destroys it
instantly. Operators cannot be too cautious in using it. A very small drop
spattered in the eye would destroy the sight. Bromine is very corrosive. A
lighted taper burns for a few moments in its vapor, with a flame green at
its base, and red at the top, and is then extinguished. It is soluble in
water, alcohol, and ether; the latter is the best solvent. With water at
32° Fahr., if forms a _hydrate_, in crystals of a fine red color. It gives
to a solution of starch an orange color. Chlorine will displace it from
all its combinations with hydrogen.
Chloride of Bromine.--Formed by transmitting a current of chlorine through
bromine, and condensing the disengaged vapors by a freezing mixture.
The factitious article is more simply formed, and is equally good as
an accelerator, but not as quick. See page 25, Part I. M. Bissou, a
Frenchman, found that the real chloride of bromine is so sensitive, that
Daguerreotype proofs are taken by it in half a second. He succeeded in
taking persons and animals in the act of walking.
Bromic Acid may be obtained by pouring sulphuric acid upon a dilute
solution of bromide of baryta, and evaporating. No interest.
Bromide of Baryta.--Boil of protobromide of iron with moist carbonate
of baryta; carefully evaporate and it will crystallize in white rhombic
prisms, which have a bitter taste, are slightly deliquescent, and soluble
in water and alcohol.
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