The Daguerreian Journal, Vol. I, No. 8, March 1, 1851Various
Science
The Daguerreian Journal, Vol. I, No. 8, March 1, 1851
Various
Daguerreotype; Photography -- Periodicals
poured off, and the precipitate is washed with water. Before throwing away
the liquid, fresh lime-water should be added to it; and if the dark hue
recurs, the precipitate must be allowed to subside again; if no change
takes place, it may be inferred that the silver is all extracted. The
oxide of silver should not be dried, but be kept in bottles with water.
* * * * *
POTASSIUM.
CYANIDE OR SIMPLE CYANURET OF POTASSIUM.
Before entering into the preparation of this ingredient, I may
mention that the _prussiate of potash_ of commerce has, by many young
experimentalists, been mistaken for the above article, because it is
often sold, by those unacquainted with chemical technicalities, under
the name of _cyanuret of potassium_. It is, in chemical parlance, termed
_ferro-cyanuret_, from its containing a certain portion of iron; and
differs in its properties, very materially, from the _simple_ salt. It
is of a bright yellow color, and is converted into the colorless, simple
cyanuret in the following manner:
Take 4 ounces of the yellow prussiate, break it in small pieces, and well
dry it on a plate of iron; then reduce it in a mortar to exceedingly fine
powder. Dry and pound in like manner one and a-half oz. of carbonate
of potash. Incorporate the two ingredients thoroughly. Place a Hessian
crucible in the fire; and when it attains a red heat, throw into it the
prepared mixture, and closely cover the crucible. Keep up the heat, and
the contents of the crucible will soon fuse; and the fluid mass will
become red-hot. After this, immerse in it, from time to time, a hot glass
rod; the mass which adheres, is in the early stages of the process brown
on cooling; as the heat is continued, it appears yellowish, and finally,
colorless and transparent. The operation is then complete: the crucible
must be removed; and after its contents have been allowed to settle, the
fused mass may be poured off; the greater portion of which consists of the
_simple cyanuret of potassium_. This salt is very deliquescent, and must
therefore be retained in close bottles: it will readily be recognized by
its powerful odor,--that noticed in peach blossoms. The mere mention of
prussic acid entering largely into its composition, will be sufficient to
induce my reader to exercise common caution in handling it.
Having these ingredients prepared, take one pint of pure rain or distilled
water; add to it two ounces of the cyanuret of potassium, shake them
together occasionally, until the latter is entirely dissolved; and allow
the liquid to become clear. Then add a quarter of an ounce of oxide of
silver, which will very speedily dissolve; the dissolution may be hastened
by heat, and after a short time, a clear transparent solution will be
obtained.--_Walker._
* * * * *
STEREO-CHROMIC PAINTING.
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