The Dyeing of Cotton Fabrics: A Practical Handbook for the Dyer and StudentBeech, Franklin
Science
The Dyeing of Cotton Fabrics: A Practical Handbook for the Dyer and Student
Beech, Franklin
Dyes and dyeing -- Cotton
_Stock Liquor._--Soda zinc vat: Put in a tub 26 gallons cold water, 15
lb. zinc powder ground into a paste with 6 gallons water, then stir in 8
gallons bisulphite of soda at 60 deg. Tw., stir well, keeping the heat down
as much as possible, after which add 8 pints caustic soda lye at 70 deg. Tw.
and 14 pints 20 per cent. liquor ammonia. When all is thoroughly mixed
add 30 lb. indigo, ground into a paste with 7 gallons water, allow to
stand for half an hour, then add water to make 100 gallons, stir at
intervals for twelve hours or so, when the stock liquor will be ready
for use.
This is used to make the vat in the same way as the first above
described. It is needful before adding the stock liquor in making a vat
to destroy any oxygen or air which is present in the vat. This may most
conveniently be done by adding thereto a solution of hydrosulphite of
soda, which may be made by mixing 4-1/2 lb. zinc dust with 5 gallons of
water and 3 gallons bisulphite of soda at 70 deg. Tw., stirring well, so
that the temperature does not rise too high, there is then added 2 pints
caustic soda and 3 pints liquor ammonia, 20 per cent.; when all is
dissolved, water is added to make up 13 gallons.
Should the vat show signs of becoming charged with indigo, indicated by
its becoming of a green colour, a little of this hydrosulphite added
from time to time will correct it.
The hydrosulphite-indigo vat made by either of the two methods indicated
above works well, and with due care may be kept in work for months. It
gives good shades of indigo, although some dyers consider that these
have not the rich bronze hue got from the lime and copperas vat. The
shades are rather faster to rubbing.
It has been proposed to employ the dye-stuff indophenol in conjunction
with indigo, in which case the method of making the vat is with zinc,
bisulphite of soda, caustic soda and ammonia as last described, only in
place of using all indigo a mixture of 22 lb. indigo and 7-1/2 lb.
indophenol is used. Good blue shades of considerable fastness can thus
be got.
_Aniline Black._--This black is produced direct upon the cotton fibre by
various processes which entail the oxidation of aniline. The chemical
composition and constitution of aniline black has not yet been worked
out. It is not by any means an easy colour to dye, but still with
careful attention to carrying out the various operations in detail
excellent results can be attained.
Aniline black is the fastest black which is known, it resists when well
dyed exposure to air and light, is quite fast to washing and soaping.
Its disadvantages are that there is, with some methods of working, a
tendency to tender the cotton fibre, making it tear easily; secondly, on
exposure to air it tends to turn green, this however only happens when
the black has not been dyed properly.
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