The Dyeing of Cotton Fabrics: A Practical Handbook for the Dyer and StudentBeech, Franklin
Science
The Dyeing of Cotton Fabrics: A Practical Handbook for the Dyer and Student
Beech, Franklin
Dyes and dyeing -- Cotton
At the present day it is perhaps without doubt the most used of all
blacks. The methods for producing it are many and varied, the following
recipes show how some of the finest aniline blacks can be dyed:--
Ungreenable black is formed when the aniline is by the action of the
oxidising agents converted into a substance named nigraniline. This
compound when formed will not turn green on the fibre under the
influence of acids.
1. The most usual oxidising agent employed for dyeing aniline black is
bichromate of soda, which salt will be found much better for all
purposes than bichromate of potash. Two separate solutions are prepared:
(1) 61 lb. aniline, 9 lb. hydrochloric acid and 10 gallons of water; and
(2) 12 lb. bichromate of soda and 20 gallons of water. After cooling,
equal quantities of these solutions are mixed and the cotton worked
rapidly through the mixture, in a few minutes it assumes a bronze black.
The material is then wrung out and steamed for twenty minutes at 3-1/2
lb. pressure, which process renders it jet black and also ungreenable.
2. Another aniline black: For 100 lb. cotton use 11 lb. aniline oil, 15
lb. bichromate of soda, 40 lb. hydrochloric acid and 160 gallons water
or 12 lb. sulphuric acid. The dye-bath is filled with the water and the
cold solution of aniline oil and a part of the hydrochloric acid in
water is first added, afterwards the bichromate is dissolved in a small
quantity of water, working cold at first and gradually rising to the
boil.
3. Another method is the following and gives a black that is fast and
ungreenable and will not rub: 10 lb. chlorate of soda, 10 lb. ammonium
chloride, 10 lb. copper sulphate, 35 lb. aniline salt, 101 lb. aniline
oil and 20 gallons water. The sodium chlorate and ammonium chloride are
dissolved in 6-1/2 gallons and the copper sulphate separately in 5-1/2
gallons water. The aniline salt is dissolved in as little hot water as
possible and neutralised with a small amount of aniline oil (10 lb.).
The solution of aniline salt is first added to the bath, then the sodium
chlorate and ammonium chloride, and lastly the copper sulphate, dilute
the whole to 14 deg. Tw. and then enter the goods. Next steam, then run
through a solution containing 10 lb. bichromate and 5 lb. soda per 100
gallons water at 160 deg. F., after which the goods are washed and dry
steamed at 15 lb. pressure.
4. A very good black is the prussiate or steam aniline black whose
cheapness should recommend it. Prepare concentrated solutions of 1-3/4
lb. aniline salt in 1 gallon water, 1-1/2 lb. ferrocyanide of potash in
3/4 gallons water and 1-1/2 lb. potassium chlorate in 1-1/2 gallons
water. Mix the solutions and work in a jigger, then steam in a Mather &
Platt apparatus for two minutes, then work hot in a jigger in a solution
of 2 lb. bichromate per 50 gallons water, dry and finish.
Either of these methods yields a good full black; with a little
experience and care perfectly uniform shades will be got.
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