The Dyeing of Cotton Fabrics: A Practical Handbook for the Dyer and Student — John Shaqi
The Dyeing of Cotton Fabrics: A Practical Handbook for the Dyer and StudentBeech, Franklin
Science
The Dyeing of Cotton Fabrics: A Practical Handbook for the Dyer and Student
Beech, Franklin
Dyes and dyeing -- Cotton
Although the chemicing is followed by a sour, which, acting on the
bleaching powder, liberates chlorine that bleaches the fabric, yet the
greatest proportion of the bleaching effect is brought about while the
pieces are being piled up into heaps between the chemicing and the sour.
In this state they should be left for some hours, covered over with a
damp sheet, care being taken that they are not left piled so long as to
become dry, as in this event there is a great risk of tendering the
cloth or fabric; it is, therefore, a good plan to moisten them with a
little water from time to time. They should not be tightly piled up, but
be as loose as possible, so that the air can get to them, as it is the
carbonic acid and other acid vapours in the air, that by acting on the
chemic causes slow liberation of chlorine, which effects the bleaching
of the goods.
(10) =White Sour.=--After the chemicing the goods are treated to a sour,
for which purpose either hydrochloric acid or sulphuric acid may be
used.
Hydrochloric acid possesses the advantage of forming a more soluble salt
of lime (calcium chloride) than does sulphuric acid (calcium sulphate),
and it has a more solvent action upon any traces of iron and other
metallic oxide stains which may be present in the goods. On the other
hand, on account of its fuming properties, it is unpleasant to work
with. The souring is done by passing the goods through an acid liquor at
2 deg. Tw. strong and piling for two or three hours, after which it is
washed. This final washing must be thorough, so that all traces of acid
and chemic are washed out, otherwise there is a tendency for the goods
to acquire a yellowish colouration.
So far the routine has been described of the so-called madder bleach,
the most perfect kind of bleach applied to cotton cloths. Besides this
two other kinds of bleach are distinguished in the trade. Turkey red and
market bleach. The former is used when the cloth or yarn is to be dyed
plain or self-coloured with delicate shades with Alizarine; the latter
is used for cloth sold in the white. As the operations involved in
producing these are identical in their method of manipulation to those
already described, it will only be necessary to give an outline of the
process for each one.
=Turkey Red Bleach=--(1) Rinse through water into a kier and boil for
two hours. (2) Lime boil for three to four hours. The amount of lime
required is rather less than what is used with the madder bleach, from
2-1/2 lb. to 3 lb, lime to each 1 cwt. of goods being quite sufficient.
(3) Souring as in the madder bleach. (4) Lye boil, using about 100 lb.
caustic soda to a ton of goods, and giving ten hours' boil. (5) Second
lye boil using about 50 lb. soda ash to a ton of goods, after which the
goods are well washed. (6) Chemicing as with the madder bleach. (7)
Souring as with the madder bleach, then washing well.
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