The Dyeing of Cotton Fabrics: A Practical Handbook for the Dyer and StudentBeech, Franklin
Science
The Dyeing of Cotton Fabrics: A Practical Handbook for the Dyer and Student
Beech, Franklin
Dyes and dyeing -- Cotton
The diazo compounds formed on the fibre are not very stable bodies. They
decompose on being exposed for any great length of time to the air,
while light has a strong action on most, if not all of them; hence it
follows that the diazotising process should not be carried out in a room
where direct, strong sunlight can enter or fall upon the goods. Then
again, after diazotising, the treated goods should not be allowed to lie
about exposed to air and light, but the operation of developing should
be proceeded with at once, otherwise the diazo body will decompose, and
weak and defective colours are liable to be obtained on subsequent
development.
For _developing_, quite a large number of substances are used. Some of
these are regular articles of commerce, others are the special
productions of certain firms, who advise their use with the dyes that
they also manufacture. These latter are sent out under such designations
as Developer B, Developer A N, or Fast-blue developer. Those most in use
are beta-naphthol for red from Primuline, and for bluish blacks from
Diamine blacks, Diazo blacks, Zambesi blacks, etc.; for dark blues from
Diamine blues, Diazo blues, etc.; for greys from Diamine blues, Neutral
grey, etc. Alpha-naphthol for dark reds from Primuline, greys from
Diamine blues, Neutral grey, etc. Phenylene diamine for blacks from
Diamine blacks, Diazo blacks, Zambesi blacks, Triamine blacks, etc.; for
dark browns from Diamine browns, Diazo browns, etc.; for light browns
from Cotton browns, Diamine cutch, Primuline, etc. Naphthylamine ether
for blues from Diamine blacks, etc. Phenol for claret from Diamine
cutch, and for gold yellow from Primuline, etc. Resorcine for orange
from Primuline, etc. Soda for browns from Diamine cutch, Diazo browns,
Zambesi browns, for orange from Diamine orange, and yellow from
Primuline.
=Beta-naphthol.=--This is by far the most important of the developers.
It is a white body, insoluble in water, but readily soluble in soda lye,
and a solution is easily made by taking 10 lb. beta-naphthol and heating
it with 10 lb. caustic soda lye of 70 deg. Tw. and 60 gallons of water. This
bath may be used as the developing bath, or it may be diluted with more
water. It is not desirable to use any more caustic soda than is
necessary to dissolve the beta-naphthol, so that the bath is not too
alkaline. To produce full shades it usually takes 1 per cent. of the
weight of the cotton of the beta-naphthol, but it is best to use the
bath as a continuous one and for the first lot of cotton use 2 per cent.
of naphthol, while for each succeeding lot only 1 per cent. more
naphthol need be added to the same bath.
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