The Dyeing of Cotton Fabrics: A Practical Handbook for the Dyer and StudentBeech, Franklin
Science
The Dyeing of Cotton Fabrics: A Practical Handbook for the Dyer and Student
Beech, Franklin
Dyes and dyeing -- Cotton
This bath is alkaline, while the diazotising bath is acid, unless,
therefore, the cotton be well washed when it is taken from the latter
bath there is a risk of the alkali of the one being neutralised by the
acidity of the other, and the naphthol being thrown out in an insoluble
form. This, of course, is easily remedied should it occur.
Developer A (Bayer) is a mixture of beta-naphthol and caustic soda in
the powder form, so that a solution is obtained by simply adding water.
Rather more (about 1-1/2 per cent.) of this is required than of
beta-naphthol.
=Alpha-naphthol= has similar properties to, and is used in the same way
as, beta-naphthol; it develops much darker and rather duller colours,
which are less fast to washing.
=Resorcine=, like naphthol, is insoluble in water, but it can be
dissolved by using either soda ash or caustic soda. The latter is
preferable, as the former is liable to give a developing bath that
froths in working, especially if much acid has been left in the cotton
from the diazotising bath. The proportions are: 10 lb. resorcine, 25 lb.
caustic soda lye of 70 deg. Tw., and 60 gallons of water; or 10 lb.
resorcine, 20 lb. soda ash, and 60 gallons of water, heated until a
solution is obtained. In the developing bath 1 per cent. of resorcine is
usually sufficient to use. It develops an orange with Primuline.
Developer F (Bayer) is a mixture of resorcine and soda ash. It requires
1-1/2 per cent, to make a developing bath.
=Phenol=, better known as carbolic acid, finds a use as a developer. It
is dissolved in caustic soda, 10 lb. phenol, 15 lb. caustic soda lye of
70 deg. Tw., and 60 gallons of water. Generally 1 per cent. is sufficient to
use as a developer. It is often called yellow developer.
=Naphthylamine ether= is used as a developer for blues in conjunction
with the Diamine blacks. It is prepared for use by dissolving in
hydrochloric acid, 10 lb. naphthylamine ether powder heated with 5 lb.
hydrochloric acid and 50 gallons water. About 1-1/4 per cent. is
required to form a developing bath. Naphthylamine ether is also sent out
in the form of a paste mixed with acid, and containing about 25 per
cent. of the actual developer.
=Fast blue developer A D= (Cassella), is amidodiphenylamine. It is
insoluble in water, but soluble in dilute acid, 10 lb. fast blue
developer A D, 5 lb. hydrochloric acid and 35 gallons of water making
the bath. To develop full shades 1 to 1-1/2 per cent, is required.
=Blue developer A N= (Cassella). The base of this is insoluble in water,
but dissolves in soda, and is probably a naphthol-sulpho acid. The
product, as met with in the market, is soluble in water, and 27 lb.
dissolved in 20 gallons of water form the bath. To produce full shades
1-1/2 per cent, is usually required.
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