_Jet Black on Wool_.--Make the dye-bath with 4 lb. Victoria Black B,
1/2 lb. Fast Yellow F Y, 10 lb. Glauber's salt, and 2 lb. sulphuric
acid, working at the boil for one hour. A very fine shade is thus
obtained, which is fast to acids, alkalies and soaping. By omitting
the Fast Yellow a blue black is obtained, while by using Acid Green
instead a greener tone is given to the black. In place of the Victoria
Black B the two other brands, 5 G, and G, of these blacks may be used.
These give equally fast blacks of a deeper and more jet black.
_Black on Wool_.--Prepare a bath with 5 lb. acetic acid, 9 deg. Tw.;
enter the wool for one hour, then lift and add 5lb. Naphthol Black 3 B,
and 1/4 lb. Indian Yellow. Re-enter the goods and boil for one hour,
wash and dry.
Many of the black dyes--Naphthol Black, Naphthylamine Blacks, (p. 092)
Naphthyl Blue Black N, Acid Black B, etc.--are capable of slowly dyeing
wool from neutral baths, that is, containing only Glauber's salt, or
rather more quickly if a little acetic acid be present. Such dyes are
very useful for dyeing heavily milled or felted fabrics, such as hat
bodies for instance, as then the dye possesses greater penetrative
properties and passes more into the substance of the fabric, which is,
therefore, better dyed through. Also they are suitable for dyeing
half-wool fabrics as will be seen on referring to the chapter dealing
with the dyeing of union or cotton-wool fabrics.
It is quite possible to dye a black on wool by using a combination of
acid and azo dye-stuffs, and below is given a recipe illustrating this
method; it is one, however, rarely adopted.
_Blue-Black on Wool_.--Prepare the dye-bath with 10 lb. Glauber's
salt, 2 lb. Patent Blue, 6 oz. Brilliant Orange, 4 oz. Amaranth, 4 oz.
Acid Violet N, 4 lb. sulphuric acid. Enter the goods at about 150 deg. F.,
raise to the boil and work to shade; lift, wash and dry. It may be of
interest to note that by using a mixture of Azo Rubine and Acid green
good blacks can be got.
There is a range of Acid and Azo dyes which are capable of dyeing from
the usual acid baths on to wool, and yet can be developed and fixed on
the fibre to good, full blacks. Types of such dyes are Anthracene
Chrome Black F F, Diamond Black F, Chrome Patent Black D G and D G G,
Fast Chrome Black, etc. Generally the blacks dyed on wool with these
dyes are very fine, have a full, bloomy appearance, and are very fast.
They are much used in dyeing hat bodies and fine cloths which have to
be very fast to the weather.
The method of application will be gleaned from the recipes given
below.
_Black_.--Prepare a dye-bath with 5 lb. Chromotrop S, 1/4 lb. Azo (p. 093)
Yellow, 50 lb. Glauber's salt. Work for one and a half hours at the
boil, then add 4 lb. sulphuric acid. Work at the boil for another half
hour, then lift. Add to the same dye-bath 3 lb. bichromate of potash.
Re-enter the goods and work at the boil for half an hour, then lift,
rinse and dry.
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