#Chemical Composition of the Pure Fibre.#--The following analyses of
purified and dried wool fibre indicate its percentage composition:--
Mulder. Bowman.
Carbon 50.5 per cent. 50.8 per cent.
Hydrogen 6.8 " 7.2 "
Nitrogen 16.8 " 18.5 "
Oxygen 20.5 " 21.2 "
Sulphur 5.4 " 2.3 "
----- -----
100.0 100.0
It is sometimes stated that wool fibre consists of a definite (p. 008)
substance, keratine, but this view cannot now be admitted, since wool
appears to be composed of a mixture or combination of several very
complex substances. It is possible and even probable that the outer
epidermal scales have a somewhat different composition to the bulk of
the fibre, but whether that is the case or not is not known with any
degree of certainty, this much can be asserted, that wool is not a
simple definite chemical compound.
Sulphur is by far the most variable constituent of wool, sometimes as
little as 1.5 and occasionally as much as 5 per cent. being found. It
appears to be always present in two different forms, one portion being
in very feeble combination and easily removed by alkalies, the
remainder, which, according to Knecht, amounts to about 30 per cent.
of the total sulphur, cannot be removed without complete
disintegration of the fibre. This latter portion does not give a black
coloration with plumbite of soda.
The amount of ash left on incinerating dry wool varies from 1 to 2 per
cent., and some have considered this inorganic matter as an essential
constituent. It consists principally of salts of potassium, calcium
and aluminum, with, of course, sulphur.
The chemical composition of the wool fibre is evidently of a most
complicated nature; judging from its behaviour in dyeing it is evident
that it may contain two bodies, one of a basic character which enables
it to combine with the azo and acid series of dyes, the other possessing
acid characters enabling it to combine with the basic dyes of the magenta
and auramine type. Dr. Knecht has isolated from the wool fibre by
extraction with alkalies and precipitation with acids a substance to
which the name of lanuginic acid has been given. It is soluble in hot
water, precipitates both acid and basic colouring matters in the form
of coloured lakes. It yields precipitates with alum, stannous (p. 009)
chloride, chrome alum, silver nitrate, iron salts, copper sulphate. It
appears to be an albuminoid body. From its behaviour with the dyes,
and with tannic acid and metallic salts, it would appear that lanuginic
acid contains both acidic and basic groups. It contains all the
elements, carbon, hydrogen, oxygen, nitrogen and sulphur, found in
wool.
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