#Action of Acids.#--Acids when dilute have but little influence on (p. 011)
the wool fibre, their tendency is to cause a separation of the scales
(see fig. 5) of the wool and so make it feel harsher. Strong acids
have a disintegrating action on the wool fibre. There is a very
considerable difference between the action of acids on wool and on
cotton, and this difference of action is taken advantage of in the
woollen industry to separate cotton from wool by the process commonly
known as "carbonising," which consists in treating the fabric with a
weak solution of hydrochloric acid or some other acid, then drying it;
the cotton is disintegrated and falls away in the form of a powder,
while the wool is not affected, sulphuric acid is used very largely in
dyeing wool with the acid- and azo-colouring matters.
[Illustration: Fig. 5.--Wool Fibre Heated with Acid.]
Nitric acid affects wool in a very similar manner to the acids named
above when used in a dilute form; if strong it gives a deep yellow
colour and acts somewhat destructively on the fibre.
Sulphurous acid (sulphur dioxide) has no effect on the actual fibre,
but exercises a bleaching action on the yellow colouring matter which
the wool contains, it is therefore largely used for bleaching (p. 012)
wool, being applied either in the form of gas or in solution in water;
the method will be found described in another chapter. Wool absorbs
sulphur dioxide in large amount, and if present is liable to retard
any subsequent dyeing processes.
#Action of Other Substances.#--Chlorine and the hypochlorites have an
energetic action on wool, and although they exert a bleaching action
they cannot well be used for bleaching wool. Hot solutions bring about
a slight oxidation of the fibre, which causes it to have a greater
affinity for colouring matters; advantage is taken of this fact in the
printing of delaines and woollen fabrics, while the woollen dyer would
occasionally find the treatment of service. A paper by Mr. E. Lodge,
in the _Journal of the Society of Dyers and Colourists_, 1892 (p. 41),
may be consulted with advantage on this subject. Wool treated with
chlorine loses its felting property, and hence becomes unshrinkable, a
fact of which advantage is taken in preparing unshrinkable woollen
fabrics.
When wool is boiled with solutions of metallic salts, such as the
sulphate of iron, chrome, aluminium and copper, the chlorides of tin,
copper and iron, the acetates of the same metals, as well as with some
other salts, decomposition of the salt occurs and a deposit of the
metallic oxide on the wool is obtained with the production of an acid
salt which remains in solution. In some cases this action is
favourably influenced by the presence of some organic acid or organic
salt, as, for examples, oxalic acid and cream of tartar (potassium
tartrate), along with the metallic salt.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account