The Economic Aspect of GeologyLeith, C. K. (Charles Kenneth)
Science
The Economic Aspect of Geology
Leith, C. K. (Charles Kenneth)
Geology, Economic
Borates, principally in the form of borax, occur in hot springs and in
lakes of volcanic regions. The Thibet deposits, and those formerly
worked at Borax Lake, California, are of this type. Certain of the
hot-spring waters of the California coast ranges and of Nevada carry
considerable quantities of boron, together with ammoniacal salts, and in
some places they deposit borax along with sulphur and cinnabar. It seems
probable (see p. 40) that these waters may come from an igneous source
not far beneath.
Most of the borax deposits of California, Nevada, and Oregon, though not
at present the largely producing ones, and probably most of the Chilean
and adjacent South American deposits, are formed by the evaporation of
desert lakes. They are products of desiccation, and in Chile are
associated with the great nitrate deposits (pp. 102-104), which are of
similar origin. The salts contained in these deposits are mainly borax,
ulexite, and colemanite. The sources of these materials are perhaps
deposits of the type mentioned in the last paragraph, or, in California,
certain Tertiary borate deposits described below. Whatever their source,
the borates are carried in solution by the waters of occasional rains to
shallow basins, which become covered with temporary thin sheets of water
or "playa lakes." Evaporation of these lakes leaves broad flats covered
with the white salts. These may subsequently be covered with drifting
sands and capillary action may cause the borates to work up through the
sands, becoming mixed with them and efflorescing at the surface. One of
the largest of the California deposits of this general class is that at
Searles Lake, from which it has been proposed to recover borax along
with the potash (pp. 113-114).
The deposits which at present constitute the principal source of
domestic borax are not the playa deposits just described, but are masses
of colemanite in Tertiary clays and limestones with interbedded basaltic
flows. The principal deposits are in Death Valley and adjacent parts of
California. The colemanite occurs in irregular milky-white layers or
nodules, mingled with more or less gypsum. The deposits are believed to
be of the replacement type, rather than ones formed contemporaneously
with the sediments. Whether they are due to magmatic solutions carrying
boric acid from the associated flows, or to surface waters carrying
materials leached from other sediments, is not clear. The crude
colemanite as mined carries an average of about 25 per cent B_2O_3; it
is treated with soda in the manufacture of borax, or with sulphuric acid
in making boric acid.
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