The Economic Aspect of GeologyLeith, C. K. (Charles Kenneth)
Science
The Economic Aspect of Geology
Leith, C. K. (Charles Kenneth)
Geology, Economic
Boron is present in minute quantities in sea water. When such water
evaporates, it becomes concentrated, along with the magnesium and
potassium salts, in the "mother liquor"; and upon complete evaporation,
it crystallizes out as boracite and other rarer minerals. Thus the
Stassfurt salts of Germany (p. 113) contain borates of this type in the
carnallite zone of the upper part of the deposits. This is the only
important case known of borate deposits of marine origin.
BROMINE
ECONOMIC FEATURES
Bromine finds a considerable use in chemistry as an oxidizing agent, in
separating gold from other metals, and in manufacturing disinfectants,
bromine salts, and aniline colors. The best known and most widely used
bromine salts are the silver bromide, used in photography, and the
potassium bromide, used in medicine to depress the nervous system.
During the war, large quantities of bromine were used in asphyxiating
and lachrymating gases.
The chief center of the bromine industry in Europe prior to 1914 was
Stassfurt, Germany. No other important commercial source in foreign
countries is known, though small quantities have been obtained from the
mother liquors of Chile saltpeter and from the seaweed, kelp, in various
countries. India has been mentioned as a possible large producer in the
future.
The United States is independent of foreign sources for bromine. The
entire domestic tonnage is produced from brines pumped in Michigan,
Ohio, West Virginia, and Pennsylvania. A large part of the output is not
actually marketed as bromine, but in the form of potassium and sodium
bromides and other salts. During the war considerable quantities of
bromine materials were exported to Great Britain, France, and Italy.
GEOLOGIC FEATURES
Bromine is very similar chemically to chlorine, and is found under much
the same conditions, though usually in smaller quantities. The natural
silver bromide (bromyrite) and the combined silver chloride and bromide
(embolite) are fairly common in the oxide zones of silver ores, but are
not commercial sources of bromine.
Bromine occurs in sea water in appreciable amounts, as well as in some
spring waters and many natural brines. When natural salt waters
evaporate, bromine is one of the last materials to be precipitated, and
the residual "mother liquors" or bitterns frequently show a considerable
concentration of the bromine. Where complete evaporation takes place, as
in the case of the Stassfurt salt deposits (p. 113), the bromine salts
are crystallized out in the final stages along with the salts of sodium,
magnesium, and potassium. The larger part of the world's bromine has
come from the mother liquor resulting from the solution and fractional
evaporation of these Stassfurt salts.
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