The Economic Aspect of GeologyLeith, C. K. (Charles Kenneth)
Science
The Economic Aspect of Geology
Leith, C. K. (Charles Kenneth)
Geology, Economic
The origin of the nitrate beds is commonly believed to be similar to
that of beds of rock salt (pp. 295-298), borax, and other saline
residues. The source of the nitrogen was probably organic matter in the
soil, such as former deposits of bird guano, bones (which are actually
found in the same desert basin), and ancient vegetable matter. By the
action of nitrifying bacteria on this organic matter, nitrate salts are
believed to have formed which were leached out by surface and ground
waters, and probably carried in solution to enclosed bodies of water.
Here they became mingled with various other salts, and all were
precipitated out as the waters of the basins evaporated. Deliquescence
and later migration of the more soluble nitrates resulted in their
accumulation around the edges of the basins. The nitrate beds are thus
essentially a product of desiccation.
While the origin just set forth is rather generally accepted, several
other theories have been advanced. It has been suggested that the
deposits were not formed in water basins, but that ground water carrying
nitrates in solution has been and is rising to the surface,--where,
under the extremely arid conditions, it evaporates rapidly, leaving the
nitrates mixed with the surface clays. One group of writers accounts for
the deposits by the fixation of atmospheric nitrogen through electrical
phenomena. Still others note the frequent presence of nitrogen in
volcanic exhalations and the association of the Chilean nitrate beds
with surface volcanic rocks; they suggest that these rocks were the
source of the nitrogen, which under unusual climatic conditions was
leached out and then deposited by evaporation.
PHOSPHATES
ECONOMIC FEATURES
The principal use of natural phosphates is in the manufacture of
fertilizers. They are also used in the manufacture of phosphorus,
phosphoric acid, and other phosphorus compounds, for matches, for
certain metallurgical operations, and for gases used in military
operations.
The material mined is mainly a phosphate of lime (tricalcium phosphate).
To make it available for plant use, it is treated with sulphuric acid to
form a soluble superphosphate; hence the importance of sulphuric acid,
and its mineral sources pyrite and sulphur, in the fertilizer industry.
A small percentage of the phosphate is also ground up and applied
directly to the soil in the raw form. Other phosphatic materials are the
basic slag from phosphatic iron ores made into Thomas-process steel,
guano from the Pacific islands, and bone and refuse (tankage) from the
cattle raising and packing countries. These materials are used for the
same purposes as the natural phosphates.
The United States is the largest factor in the world's phosphate
industry, with reference both to production and reserves.
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