The electron, its isolation and measurement and the determination of some of its propertiesMillikan, Robert Andrews
Philosophy
The electron, its isolation and measurement and the determination of some of its properties
Millikan, Robert Andrews
Electrons
Of course, the idea of a granular structure for electricity was foreign
to the two-fluid theory, and since this dominated the development of
electrical science, there was seldom any mention in connection with it
of an electrical atom, even as a speculative entity. But with Franklin
the case was different. His theory was essentially a material one, and
[Pg 15]
he unquestionably believed in the existence of an electrical particle
or atom, for he says: “The electrical matter consists of particles
extremely subtle, since it can permeate common matter, even the
densest, with such freedom and ease as not to receive any appreciable
resistance.” When Franklin wrote that, however, he could scarcely have
dreamed that it would ever be possible to isolate and study by itself
one of the ultimate particles of the electrical fluid. The atomic
theory of electricity was to him what the atomic theory of matter was
to Democritus, a pure speculation.
The first bit of experimental evidence which appeared in its favor came
in 1833, when Faraday found that the passage of a given quantity of
electricity through a solution containing a compound of hydrogen, for
example, would always cause the appearance at the negative terminal of
the same amount of hydrogen gas irrespective of the kind of hydrogen
compound which had been dissolved, and irrespective also of the
strength of the solution; that, further, the quantity of electricity
required to cause the appearance of one gram of hydrogen would always
deposit from a solution containing silver exactly 107.1 grams of
silver. This meant, since the weight of the silver atom is exactly
107.1 times the weight of the hydrogen atom, that the hydrogen atom and
the silver atom are associated in the solution with exactly the same
quantity of electricity. When it was further found in this way that all
atoms which are univalent in chemistry, that is, which combine with one
atom of hydrogen, carry precisely the same quantity of electricity, and
all atoms which are bivalent carry twice this amount, and, in general,
[Pg 16]
that valency, in chemistry, is always exactly proportional to the
quantity of electricity carried by the atom in question, it was obvious
that the atomic theory of electricity had been given very strong
support.
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