The electron, its isolation and measurement and the determination of some of its propertiesMillikan, Robert Andrews
Philosophy
The electron, its isolation and measurement and the determination of some of its properties
Millikan, Robert Andrews
Electrons
Since these enormously high X-ray frequencies must arise from electrons
which fall into extraordinarily powerful fields of force, such as might
be expected to exist in the inner regions of the atom close to the
nucleus, Moseley’s discovery strongly suggests that the charge on this
nucleus is produced in the case of each atom by adding some particular
invariable charge to the nucleus of the atom next below it in Moseley’s
table. This suggestion gains added weight when it is found that with
one or two trifling exceptions, to be considered later, Moseley’s
series of increasing X-ray frequencies is exactly the series of
increasing atomic weights. It also receives powerful support from
the following discovery.
Mendeleéff’s periodic table shows that the progression of chemical
properties among the elements coincides in general with the progression
of atomic weights. Now it was pointed out ten years ago that whenever
a radioactive substance loses a doubly charged -particle it
moves two places to the left in the periodic table, while whenever it
loses a singly charged -particle it moves one place to the
right,[149] thus showing that the chemical character of a substance
[Pg 203]
depends upon the number of free positive charges in its nucleus.
One of the most interesting and striking characteristics of Moseley’s
table is that all the known elements between sodium (atomic number 11,
atomic weight 23) and lead (atomic number 82, atomic weight, 207.2)
have been fitted into it and there are left but three vacancies within
this range. Below sodium there are just 10 known elements, and very
recent study[150] of their spectra in the extreme ultra-violet has
fixed the place of each in the Moseley progression, though in this
region the progression of atomic weights and of chemical properties is
also altogether definite and unambiguous. It seems highly probable,
then, from Moseley’s work that we have already found all except three
of the complete series of different types of atoms from hydrogen to
lead, i.e., from 1 to 82, of which the physical world is built. From
82 to 92 comes the group of radioactive elements which are continually
transmuting themselves into one another, and above 92 (uranium) it is
not likely that any elements exist.
That hydrogen is indeed the base of the Moseley series is rendered
well-nigh certain by the following simple computation. If we write
Moseley’s discovery that the square roots of the highest frequencies,
, , etc., emitted by different atoms are proportional
to the nuclear charges, , , etc., in the following
form:
Public-domain text, read in full here on John Shaqi.
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