The electron, its isolation and measurement and the determination of some of its propertiesMillikan, Robert Andrews
Philosophy
The electron, its isolation and measurement and the determination of some of its properties
Millikan, Robert Andrews
Electrons
[Pg 204]
and substitute for the observed wave-length of the
highest frequency line emitted by tungsten—a wave-length which has
been accurately measured and found to be ;
and, further, if we substitute for , 74, the atomic number
of tungsten, and for , 1, if the Moseley law were exact we
should obtain, by solving for the wave-length of the highest frequency
line which can be emitted by the element whose nucleus contains but
one single positive electron. The result of this substitution is
(millionths millimeters). Now the
wave-length corresponding to the highest observed frequency in the
ultra-violet series of hydrogen lines recently discovered by Lyman is
and there is every reason to believe from the form
of this series that its convergence wave-length—this corresponds to
the highest frequency of which the hydrogen atom is theoretically
capable—is . The agreement is only approximate, but it
is as close as could be expected in view of the lack of exact equality
in the Moseley steps. It is well-nigh certain, then, that this Lyman
ultra-violet series of hydrogen lines is nothing but the X-ray
series of hydrogen. Similarly, it is equally certain that the
X-rays series of hydrogen is the ordinary Balmer series in the visible
region, the head of which is at In other
words, hydrogen’s ordinary radiations are its X-rays and nothing more.
There is also an series for hydrogen discovered by Paschen in the
ultra-red, which in itself would make it probable that there are series
for all the elements of longer wave-length than the series, and
that the complicated optical series observed with metallic arcs are
parts of these longer wave-length series. As a matter of fact, an
[Pg 205]
series has been found for a considerable group of the elements of high
atomic number.
Thus the Moseley experiments have gone a long way toward solving the
mystery of spectral lines. They reveal to us clearly and certainly
the whole series of elements from hydrogen to uranium, all producing
spectra of remarkable similarity, at least so far as the and
radiations are concerned, but scattered regularly through the
whole frequency region, from the ultra-violet, where the lines
for hydrogen are found, all the way up to frequencies or
8,464 times as high. There is scarcely a portion of this whole field
which is not already open to exploration. How brilliantly, then, have
these recent studies justified the predictions of the spectroscopists
that the key to atomic structure lay in the study of spectral lines!
Public-domain text, read in full here on John Shaqi.
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