The electron, its isolation and measurement and the determination of some of its propertiesMillikan, Robert Andrews
Philosophy
The electron, its isolation and measurement and the determination of some of its properties
Millikan, Robert Andrews
Electrons
Faraday’s experiments had of course not furnished the data for
determining anything about how much electricity an electron represents
[Pg 28]
in terms of the standard unit by which electrical charges are
ordinarily measured in the laboratory. This is called the coulomb,
and represents the quantity of electricity conveyed in one second by
one ampere. Faraday had merely shown that a given current flowing in
succession through solutions containing different univalent elements
like hydrogen or silver or sodium or potassium would deposit weights
of these substances which are exactly proportional to their respective
atomic weights. This enabled him to assert that one and the same amount
of electricity is associated in the process of electrolysis with an
atom of each of these substances. He thought of this charge as carried
by the atom, or in some cases by a group of atoms, and called the group
with its charge an “ion,” that is, a “goer,” or “traveler.” Just how
the atoms come to be charged in a solution Faraday did not know, nor
do we know now with any certainty. Further, we do not know how much of
the solvent an ion associates with itself and drags with it through the
solution. But we do know that when a substance like salt is dissolved
in water many of the neutral NaCl molecules are split up by some action
of the water into positively charged sodium (Na) ions and negatively
charged chlorine (Cl) ions. The ions of opposite sign doubtless are
all the time recombining, but others are probably continually forming,
so that at each instant there are many uncombined ions. Again, we know
that when a water solution of copper sulphate is formed many of the
neutral CuSO₂ molecules are split up into positively charged Cu ions
and negatively charged SO₄ ions. In this last case too we find that the
same current which will deposit in a given time from a silver solution
[Pg 29]
a weight of silver equal to its atomic weight will deposit from the
copper-sulphate solution in the same time a weight of copper equal to
exactly one-half its atomic weight. Hence we know that the copper ion
carries in solution twice as much electricity as does the silver ion,
that is, it carries a charge of two electrons.
But though we could get from Faraday’s experiments no knowledge about
the quantity of electricity, , represented by one electron, we
could get very exact information about the ratio of the ionic charge
to the mass of the atom with which it is associated in a given
solution.
Public-domain text, read in full here on John Shaqi.
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