The electron, its isolation and measurement and the determination of some of its properties — John Shaqi
The electron, its isolation and measurement and the determination of some of its propertiesMillikan, Robert Andrews
Philosophy
The electron, its isolation and measurement and the determination of some of its properties
Millikan, Robert Andrews
Electrons
Thus, even though the facts of electrolysis give us no information at
all as to how much of a charge one electron represents, they do
tell us very exactly that if we should take as many times as
there are molecules in a gram molecule we should get exactly 9,650
absolute electromagnetic units of electricity. This is the amount of
electricity conveyed by a current of 1 ampere in 10 seconds. Until
quite recently we have been able to make nothing better than rough
guesses as to the number of molecules in a gram molecule, but with the
aid of these guesses, obtained from the Kinetic Theory, we have, of
course, been enabled by (1) to make equally good guesses about .
Those guesses, based for the most part on quite uncertain computations
as to the average radius of a molecule of air, placed anywhere
[Pg 32]
between and . It was in this
way that G. Johnstone Stoney in 1874 estimated at .
In O. E. Meyer’s Kinetische Theorie der
Gase (p. 335; 1899), , the number of molecules in a cubic
centimeter, is given as . This would correspond to
. In all this is the charge carried by a
univalent ion in solution and or is a pure number, which is
a characteristic gas constant, it is true, but the analysis has nothing
whatever to do with gas conduction.
III. THE NATURE OF GASEOUS CONDUCTION
The question whether gases conduct at all, and if so, whether their
conduction is electrolytic or metallic or neither, was scarcely
attacked until about 1895. Coulomb in 1785 had concluded that after
allowing for the leakage of the supports of an electrically charged
conductor, some leakage must be attributed to the air itself, and
he explained this leakage by assuming that the air molecules became
charged by contact and were then repelled—a wholly untenable
conclusion, since, were it true, no conductor in air could hold a
charge long even at low potentials, nor could a very highly charged
conductor lose its charge very rapidly when charged above a certain
potential and then when the potential fell below a certain critical
value cease almost entirely to lose it. This is what actually occurs.
Despite the erroneousness of this idea, it persisted in textbooks
written as late as 1900.
Warburg in 1872 experimented anew on air leakage and was inclined
to attribute it all to dust particles. The real explanation of gas
conduction was not found until after the discovery of X-rays in 1895.
[Pg 33]
The convincing experiments were made by J. J. Thomson, or at his
instigation in the Cavendish Laboratory at Cambridge, England. The new
work grew obviously and simply out of the fact that X-rays, and a year
or two later radium rays, were found to discharge an electroscope,
i.e., to produce conductivity in a gas. Theretofore no agencies had
been known by which the electrical conductivity of a gas could be
controlled at will.
Public-domain text, read in full here on John Shaqi.
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