The Elements of Blowpipe AnalysisGetman, Frederick Hutton
Science
The Elements of Blowpipe Analysis
Getman, Frederick Hutton
Blowpipe
Before the Bp. on Ch. with Na_{2}CO_{3}. Reduced with emission of
arsenical fumes.
In ignition tube with Na_{2}CO_{3} and Ch. Volatilizes, forming a
mirror-like deposit of metallic As in the cooler part of tube.
In flame on platinum wire____
With borax bead on platinum wire____
With Co(NO_{3})_{2}.____
4. ~Bismuth, Bi_{2}O_{3}.~--Before the Bp. on Ch. Yields a
coating--orange-yellow when hot, lemon-yellow when cold. The yellow
coating usually has a white outline.
Before the Bp. on Ch. with Na_{2}CO_{3}. Easily reduced to metallic
bismuth. Yellow bead brittle, but less so than antimony.
In ignition tube with Na_{2}CO_{3} and Ch.____
In flame on platinum wire____
With borax bead on platinum wire. In O. F. small quantity dissolves to a
clear yellow glass, which becomes colorless when cold.
With Co(NO_{3})_{2}____
5. ~Cadmium, CdO.~--Before the Bp. on Ch. Gives a coating on the coal.
Reddish-brown when cold. Very volatile.
Before the Bp. on Ch. with Na_{2}CO_{3}. Readily reduced. The metal
volatilizes easily, giving the characteristic coating.
In ignition tube with Na_{2}CO_{3} and Ch.____
In flame on platinum wire____
With borax bead. In O. F. dissolves to a clear yellowish bead, colorless
when cold.
With Co(NO_{3})_{2}____
6. ~Chromium, Cr_{2}O_{3}.~--Before the Bp. on Ch. No change.
Before the Bp. on Ch. with Na_{2}CO_{3}. Cannot be reduced. Soda sinks
in Ch. and a green colored mass remains.
In ignition tube with Na_{2}CO_{3} and Ch.____
In flame on platinum wire____
~With borax bead.~ Dissolves slowly but colors intensely. Yellow while
hot, green when cold.
With microcosmic salt bead. Colors red when hot, green when cold.
With Co(NO_{3})_{2}____
7. ~Cobalt, CoO.~--Before the Bp. on Ch. In O. F. unchanged. In R. F. is
reduced to the metal and is magnetic.
Before the Bp. on Ch. with Na_{2}CO_{3}. Reduced to a gray magnetic
mass.
In ignition tube with Na_{2}CO_{3} and Ch.____
In flame on platinum wire____
With borax bead on platinum wire. In O. F. colors very intensely blue,
both hot and cold.
With Co(NO_{3})_{2}____
8. ~Copper, CuO.~--Before the Bp. on Ch. Fuses to a black globule, which
can be reduced with some difficulty.
Before the Bp. on Ch. with Na_{2}CO_{3}. Readily reduced to metallic
bead, which is red in color, hard, malleable.
In ignition tube with Na_{2}CO_{3} and Ch.____
In flame on platinum wire. Colors flame emerald-green.
With borax bead on platinum wire. In O. F. green when hot, blue when
cold.
With Co(NO_{3})_{2}____
9. ~Iron, Fe_{2}O_{3}.~--Before the Bp. on Ch. In O. F. unchanged. In R.
F. becomes black and magnetic.
Before the Bp. on Ch. with Na_{2}CO_{3} Reduced to a metallic powder,
magnetic.
In ignition tube with Na_{2}CO_{3} and Ch.____
In flame on platinum wire____
With borax bead on platinum wire. In O. F. red while hot, yellow when
cold.
With Co(NO_{3})_{2}____
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