The Elements of Blowpipe AnalysisGetman, Frederick Hutton
Science
The Elements of Blowpipe Analysis
Getman, Frederick Hutton
Blowpipe
~Tetrahedrite~, 4 CuS + Sb_{2}S_{3}.--Frequently contains silver, iron,
mercury, and zinc. H = 3.0-4.0, G = 4.5-5. Color, steel-gray to
iron-black. Heated in an ignition tube fuses and gives a sublimate of
antimonious oxide. When mercury is present this condenses in the upper
part of the tube, forming the characteristic mirror. Before the Bp. on
Ch. it fuses readily to a metallic globule, emitting dense white fumes;
zinc and antimony coatings are deposited on the Ch. After long ignition
before the Bp., if the mineral is finely powdered and mixed with
Na_{2}CO_{3} and KCN, the ore is reduced to the metal.
~Cuprite~, Cu_{2}O, Cu . 89, O . 11.--
H = 3.5-4.0, G = 5.5-6.15.
Color, intense crimson-red. Before the Bp. on Ch. blackens and fuses
quietly, and finally yields a metallic globule of copper. Before the Bp.
on Ch. with Na_{2}CO_{3} and KCN it is easily reduced.
~Malachite~, 2 CuO + CO_{2} + H_{2}O, CuO . 72, CO_{2} . 20, H_{2}O . 8.--
H = 3.5-4.0, G = 3.90-4.03.
Color, bright green. Occurs generally in mammillated concretions.
Lustre, shining and fracture, silky. Heated in an ignition tube yields
water and blackens. Before the Bp. on Ch. it fuses to a metallic
globule. Before the Bp. on Ch. with Na_{2}CO_{3} and KCN it is easily
reduced. With borax bead gives characteristic coloration.
~Azurite~, 3 CuO + 2 CO_{2} + H_{2}O, CuO . 69, CO_{2} . 26, H_{2}O . 5.--
H = 3.5-4.0, G = 3.77-3.83.
Color, azure-blue. Occurs usually in crystallized or globular masses.
Lustre, earthy or vitreous. Before the Bp. and with other reagents
behaves like malachite.
~Chrysocolla~, CuO + SiO_{2} + 2 H_{2}O, SiO_{2} . 34.2, CuO . 45.3,
H_{2}O . 20.5.--H = 2.0-3.0, G = 2. Color, bluish-green, closely
resembling malachite. Occurs usually as an incrustation, its surface
being very smooth, like enamel. In an ignition tube it blackens and
yields water. Before the Bp. on Ch. in O. F. it blackens, coloring the
flame bright green; in the R. F. it turns red. Before the Bp. on Ch.
with Na_{2}CO_{3} yields metallic copper. In borax bead it reacts for
copper.
~Atacamite~, CuCl_{2} + 3 CuO_{2}H_{2}--Cl . 16.6, O . 20.3, Cu . 50.1,
H_{2}O . 13.0.--
H = 3.0-3.5, G = 3.75-3.77.
Color, green to blackish green. Lustre, adamantine to vitreous. In an
ignition tube yields water. Before the Bp. on Ch. colors flame blue.
Before the Bp. on Ch. with Na_{2}CO_{3} and KCN is reduced to the metal.
In borax bead it reacts for copper.
ORES OF IRON
~Limonite~, 2 Fe_{2}O_{3} + 3 H_{2}O, Fe_{2}O_{3} . 86, H_{2}O . 14.--H =
5.0-5.5, G = 3.6-4.0. Color, brown to ochre-yellow. Earthy or
semi-metallic in appearance. In an ignition tube yields water. Before
the Bp. on Ch. infusible. In borax bead reacts for iron.
~Hematite~, Fe_{2}O_{3}, Fe . 70, O . 30.--
H = 5.5-6.5, G = 4.9-5.3.
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