The Elements of Blowpipe AnalysisGetman, Frederick Hutton
Science
The Elements of Blowpipe Analysis
Getman, Frederick Hutton
Blowpipe
Color, bluish gray, slowly tarnishing. Lustre, metallic. Crystals in the
form of cubes. Heated in an ignition tube it sometimes decrepitates and
yields a sublimate of sulphur. Before the Bp. on Ch. easily reduced to
the metallic state, the Ch. becoming coated with sulphate and oxide of
lead. The metallic globule usually contains a little silver. To separate
this, the process known as "cupellation" is employed. A hole is bored
into the Ch. about 1 cm. in diameter and about 6 mm. deep. Into this
hole is placed a stiff paste made by mixing finely pulverized bone-ash
with a little soda and water. This paste is pressed in hard, and then
the surface is smoothed off, and the centre is slightly depressed with
the rounded end of a glass rod. The charcoal so prepared is set in a
warm place to allow the paste to dry. When the paste is quite dry the
small globule of lead is placed in the depression in the centre of the
bone-ash "cupel," and is there exposed to the O. F. from the Bp. The
lead is oxidized and is absorbed by the bone-ash, while any silver
present will remain in the central depression as a bright shining bead.
~Cerusite~, PbCO_{3}, PbO . 84, CO_{2} . 16.--H = 3.0-3.5, G = 6.46-6.57.
Color, white, gray, or yellow. Lustre, adamantine. Crystallizes in
prismatic needles. When heated in an ignition tube carbon dioxide is
evolved and the residue turns yellow. Before the Bp. on Ch. readily
reduced to metallic lead.
~Anglesite~, PbSO_{4}, PbO . 74, SO_{3} . 26.--H = 2.0-3.0, G = 6.12-6.39.
Color, yellow, gray, and brown. Lustre, adamantine, resinous. Heated in
an ignition tube decrepitates, and sometimes yields a little water.
Before the Bp. on Ch. fuses to a clear bead, which on cooling becomes
opaque. Before the Bp. on Ch. with Na_{2}CO_{3} is reduced to the metal
giving a yellow coating. The Na_{2}CO_{3} absorbed by the coal reacts
for S.
ORES OF MANGANESE
~Pyrolusite~, MnO_{2}, Mn . 63.2, O . 36.8.--H = 2.0-2.5, G = 4.82. Color,
iron-black to steel-gray. Lustre, non-metallic. Heated in an ignition
tube yields generally a little water, and if the temperature be high
enough, oxygen is evolved. Before the Bp. on Ch. infusible. In borax
bead gives characteristic color.
~Psilomelane~, Mn_{2}O_{3} + H_{2}O.--
H = 5.5-6.0, G = 3.7-4.7.
Color, iron-black to steel-gray. Generally resembles pyrolusite, but is
distinguished from it by its superior hardness. It frequently contains
BaO and Li_{2}O. It behaves before the Bp. like pyrolusite.
~Wad~ (Bog Manganese).--This mineral is essentially MnO_{2}, MnO, and
H_{2}O, with small quantities of Fe_{2}O_{3}, Al_{2}O_{3}, BaO, SiO_{2},
etc., associated with it.
H = 0.5-6.0, G = 3.0-4.2. Color, dull black. Heated in an ignition tube
yields water in abundance, otherwise it behaves like pyrolusite.
ORES OF MERCURY
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