The Elements of Blowpipe AnalysisGetman, Frederick Hutton
Science
The Elements of Blowpipe Analysis
Getman, Frederick Hutton
Blowpipe
The microcosmic salt bead dissolves almost every oxide except silica,
SiO_{2}, and this is seen to float about in the melted mass. This is
used as a test for silica.
~Examination with Co(NO_{3})_{2}.~--If after examination on the Ch. _per
se_, a white infusible residue remains, it is moistened with a drop of
cobalt nitrate Co(NO_{3})_{2} and re-ignited before the Bp., when a
change of color will be observed. This change in color is owing to the
fact that the heat of the Bp. flame decomposes the cobalt nitrate,
nitric acid being driven off, and the remaining CoO forming with the
oxide of the residue a colored mass.
_Illustrations._ Ignite before the Bp. on Ch. the following
oxides,--allow to cool, add a drop of Co(NO_{3})_{2}, re-ignite, and
note color,--aluminum, magnesium, zinc, and calcium.
Care should be taken to thoroughly ignite before adding the cobalt
nitrate solution.
With the six methods of examination just given almost every simple
substance can be detected, but should any doubt remain, a few simple
tests in the "liquid way" will be sufficient to substantiate the
blowpipe examination.
CHAPTER III
GENERAL REACTIONS FOR THE DETECTION OF THE METALLIC ELEMENTS IN SIMPLE
COMPOUNDS
For the sake of convenience, rather than for scientific reasons, the
following compounds have been arranged in alphabetic order. Also the
oxides of the elements have been taken, since they exhibit the reactions
to best advantage.
The student should work through carefully each one of the tests and
satisfy himself as to the characteristic reactions of the various
elements, for only in this way can he expect to recognize the substances
when presented to him as "unknowns." It is advisable to provide a
note-book and rule it as follows:--
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