The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
«The General Character and the Definition of the Colloidal
Condition.»—Recent investigations have shown that the colloidal
condition is possible, not only for a limited class of substances,
but is, in general, possible for all substances.[252] Thus, even such
an eminently crystallizable, readily soluble (in water) substance
as sodium chloride may be obtained, under certain conditions, in
colloidal suspension in benzene,[253] in which it is insoluble.
For our purposes it will be sufficient to define the colloidal
condition, on the basis of these results, as the condition of an
insoluble substance in which, as far as ordinary observation and the
common methods for separation of heterogeneous phases (filtration,
sedimentation, etc.) are concerned, ‹the substance appears to be
present in a homogeneous clear solution›, whereas ‹in reality› it is
present in a ‹heterogeneous mixture›. An extremely finely divided
solid suspended in a liquid, or an emulsified liquid suspended in
another liquid, are the most common types[254] of such mixtures.
[p131]
«Relations to Analysis.»—Since the colloidal condition of insoluble
substances interferes with the precipitation of the latter, and
with their separation by filtration from the liquids in which
they are suspended, and since the majority of the separations and
tests of analytical chemistry depend on the successful formation
of precipitates and on their successful separation by filtration,
analytical chemistry is primarily[255] concerned with the colloidal
condition as a condition that is to be ‹avoided as completely as
possible› in order to escape error. In other fields of chemistry,
notably in physiological chemistry and in some branches of technical
chemistry, it is a source of effects so momentous and specific that
a new branch of chemistry, the chemistry of colloids,[256] has grown
out of the investigations of its relations and laws. The present
discussion will be limited to the presentation of such of the
fundamental facts concerning the colloidal condition as are of chief
importance in analytical work.[257]
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