The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
[244] This process of separation of substances, which do not pass
through membranes, from such as do, is called ‹dialysis›. It was
first used by Graham, ‹Trans. Royal Soc.›, London, «151», 183–224
(1861) («Stud.»).
[245] Graham made the first extended investigations in this field:
‹Trans. Royal Soc.›, «151», 183 (1861); ‹J. Chem. Soc.› (London),
«17», 318 (1864) («Stud.»). He found that amorphous, gelatinous
bodies like ferric hydroxide, aluminium hydroxide, silicic acid,
gelatine, glue, dextrin, caramel, albumen and similar bodies do
not pass through membranes and may be obtained by dialysis in the
‹colloidal› condition. Such substances were called "colloids" by
Graham, the name referring to the Latin for gelatine. Substances
which pass through membranes readily were found by Graham to
resemble in behavior such bodies as are crystallizable when solid;
such compounds were classified by him as "crystalloids." That
liquids containing substances in the colloidal condition (‹e.g.›
arsenious sulphide, gold, silver and many other substances) may be
prepared by methods other than dialysis, was found later by many
investigators and, in a few cases, previous to Graham, ‹e.g.› by
Faraday, ‹loc. cit.› A brief history of the chemistry of colloids
is found as an introduction to Wo. Ostwald's ‹Kolloidchemie›, pp.
1–63 (1909).
[246] ‹Cf.› Wo. Ostwald, ‹loc. cit.›, p. 193.
[247] Before Graham's time, and for the few colloidal liquids then
known, this view was held by such men as J. B. Richter, Berzelius
and Faraday (‹loc. cit.›) (‹cf.› Wo. Ostwald, ‹loc. cit.›, p. 19).
The first extended experimental investigation in support of it was
made by Barus and Schneider, ‹Z. phys. Chem.›, «8», 278 (1891).
Bredig was also an early and consistent champion of this view
(‹vide› his ‹Anorganische Fermente›, 1901).
[248] ‹Cf.› Wo. Ostwald, ‹loc. cit.›, pp. 102–114. Graham
considered "colloidal silicic acid a liquid miscible with water in
all proportions." According to modern ideas, no true miscibility
exists, but a suspension or emulsion is formed (see Ostwald, p.
237).
[249] Siedentopf and Zsigmondy, ‹Drude's Annalen›, «10», 1 (1903).
Zsigmondy, ‹Colloids and the Ultramicroscope› (1909), Chapter V.
[250] Zsigmondy, ‹Z. für Elektrochem.›, «8», 684 (1902); Siedentopf
and Zsigmondy, ‹loc. cit.›
[251] Zsigmondy, ‹loc. cit.›, p. 161. A µµ is 1E−6 mm. The hydrogen
molecule is considered to have a diameter of 0.1 µµ (O. E. Meyer),
the alcohol molecule one of 0.5 µµ (Zsigmondy, ‹loc. cit.›, plate
IV, p. 157).
[252] Weimarn, ‹Chem. Zentralblatt›, 1907, II, p. 1293.
[253] Paal, ‹Ber. d. chem. Ges.›, «39», 1436, 2859 (1906).
[254] Other varieties of heterogeneous colloidal mixtures are
tabulated by Wo. Ostwald, ‹loc. cit.›, p. 96.
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