The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
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The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
[255] The "Cassius' purple" test for gold is an instance where the
colloidal condition is used in analysis for a positive test. See
Wo. Ostwald, ‹loc. cit.›, p. 68, for other, similar applications
for positive tests.
[256] ‹Vide› Wo. Ostwald's ‹Kolloidchemie›, 1909, and the
references given by Noyes, ‹loc. cit.›, p. 86.
[257] A general discussion of the preparation and properties of
colloidal mixtures is given by A. A. Noyes, ‹J. Am. Chem. Soc.›,
«27», 86–104 (1905) («Stud.»).
[258] Picton and Linder, ‹J. Chem. Soc.› (London), «61», 160
(1892), «67», 63 (1895), «71», 568 (1897), etc., and others. Wo.
Ostwald, ‹loc. cit.›, p. 240, gives a list of references.
[259] The arrangement of the experiment is described by Noyes,
‹loc. cit.›, p. 98.
[260] ‹Cf.› Wo. Ostwald, ‹loc. cit.›, p. 108. Billitzer has found
that gelatine is positive in acid solution, negative in alkaline,
‹Z. phys. Chem.›, «51», 147 (1905). The charges are, however,
relatively small ones.
[261] Billitzer, ‹Z. f. Elektrochem.›, «8», 638 (1902). This
is probably true of all amphoteric colloids (Chapter X); it is
also true of many other substances, which are not pronouncedly
amphoteric. (‹Cf.› Perrin, ‹Comp. rend.›, «136», 1388 (1903);
Billitzer, ‹Z. phys. Chem.›, «51», 157 (1905).)
[262] Hardy, ‹J. of Physiology›, 24, 288 (1899); ‹Z. phys. Chem.›,
«33», 387 (1900).
[263] Billitzer, ‹loc. cit.›, p. 159; Müller's ‹Allgemeine Chemie
der Kolloide›, 1907, p. 79.
[264] See below, p. 134.
[265] In a slightly acid solution colloidal silicic acid is
negatively charged; in a ‹strong› acid solution, positively—a
relation which agrees with its ‹predominantly acid character›.
[266] The general class of substances, showing both basic and acid
properties, of which albumen is a derivative, is described in a
footnote on glycocoll, Chapter X, p. 188.
[267] Hardy, ‹loc. cit.›
[268] J. Loeb, University of California Publications, ‹Physiology›,
«2», 149 (1904).
[269] Very little is known about the nature of contact electricity.
It is even doubtful whether it is different, in principle, from
ionization.
[270] W. Ostwald, Lehrbuch der Chem., «2», (1) 553 (1903).
[271] Hardy, ‹Proc. Royal Soc.›, «66», 110 (1899); ‹Z. phys.
Chem.›, «33», 391 (1900).
[272] Picton and Linder, ‹J. Chem. Soc.› (London), «67», 63 (1895).
[273] Whitney and Ober, ‹J. Am. Chem. Soc.›, «23», 852–856 (1901)
(Stud.).
[274] Picton and Linder, ‹loc. cit.› «71», 572 (1897); Lottermoser,
‹Anorganische Kolloide›, p. 76; Biltz, ‹Ber. d. chem. Ges.›, «37»,
1095 (1904).
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