The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
It appears, however, that while the soundness of this theoretical
development of the relations expressed by the solubility-product must
be questioned, nevertheless as a ‹matter of experiment›, the ‹product
of the ion concentrations› of a difficultly soluble salt is found,
in dilute solutions, to be a constant, or sufficiently close to a
constant to satisfy all but the most rigorous requirements.[295]
It is, in fact, quite evident, that a ‹decreasing value for the
second term of the ratio I›—namely, for [CH_{3}COOAg], the molecular
solubility of the salt—as the total concentration of the electrolytes
present increases, together with an ‹increasing value for the whole
ratio I› under the same conditions, are ‹not incompatible with a
constant value› of the first term of the ratio. That is, ‹the product
of the ion concentrations›, [CH_{3}COO^{−}] × [Ag^{+}], ‹may well
remain constant› (equation IV), or approximately constant, in dilute
salt solutions, even if equations I and III do not hold for salt
solutions. [p143]
Whether in the case of all difficultly soluble salts, as the total
salt concentration increases, the increasing values of the chemical
equilibrium ratio (equation I) will be so nicely balanced by the
decreasing values of the molecular solubility, that the first term
of the first ratio (the solubility-product) will always be constant,
is a question demanding further extended investigation.[296] The
range of the investigation must be extensive, because it must include
several other classes[297] of salts (‹e.g.› Me_{2}X, MeY_{2}, etc.),
for which the first equation has a different form; for instance, for
Me_{2}X,
[Me^{+}]^2 × [X^{2−}] / [Me_{2}X] = K.
For the present we must remain content with the result of the
past investigations and consider the principle of the constant
solubility-product to be essentially an empirical one. It is an
extremely convenient condensation, into a very simple mathematical
form, of the main factors involved in the precipitation and solution
of difficultly soluble salts, acids, and bases. It should be used
with due knowledge of its character and limitations.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account