The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
Such precautions are still more important in the case of precipitates
which are somewhat more soluble than is barium sulphate, and in such
cases the question must be considered, whether as a washing fluid,
some solution may not be used, which contains an ion in common
with the precipitate, and which has, therefore, according to the
principle of the solubility-product, a very much smaller dissolving
power for the precipitate in question than pure water. That is a
resource of the analyst to which recourse is occasionally taken.
Lead sulphate, for instance, is washed with a very dilute solution
of sulphuric acid, rather than with pure water;[312] potassium
cobaltinitrite, K_{3}Co(NO_{2})_{6}, which is used in the separation
of cobalt from nickel, is washed[313] with a ten per cent solution of
potassium acetate, containing a little potassium nitrite. Ammonium
phosphomolybdate, used in determinations of phosphates, is washed
with a solution of ammonium nitrate. [p149]
The use of such solutions for washing precipitates is limited by the
necessity, first, of avoiding salts which interfere with subsequent
operations (‹e.g.› which would leave nonvolatile residues in the
subsequent ignition of a precipitate, that is to be weighed after
ignition) and, second, of avoiding the loss of precipitate by the
formation of complex ions between an ion of the precipitate and a
component of the washing mixture (see p. 148). But wherever such
complications can be excluded, the method is a desirable one.
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