The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
It has sometimes been recommended to wash a precipitate with a
‹saturated› aqueous solution of the precipitate itself, in place of
with pure water. It was reasoned that the solution, being already
saturated with the salt, would not be able to dissolve any of the
precipitate obtained. That is true; but if a saturated solution of
a salt, MeX, is placed on a filter still holding an excess of the
precipitant, ‹i.e.› one of the ions, say X, of the precipitate, then
this excess may cause supersaturation of the saturated washing fluid
and some of the salt may be precipitated out of the washing fluid.
The method, as commonly employed, has therefore the inherent fault,
theoretically at least, of being liable to give too high results.
If it is to be employed without error, precautions must be taken
first to remove, from the precipitate and filter, the mother liquor
(containing the excess of precipitant) as completely as possible.
If in a given case this can be accomplished, then the danger of
precipitating any of the salt (MeX) from the saturated solution is
avoided, and the precipitate (MeX ↓) may then be further washed
with a saturated solution of the same salt (MeX), with advantage,
in certain cases. Thus, in the Lindo-Gladding method[314] of
determining potassium in the form of potassium chloroplatinate, the
source of error, just discussed, has been avoided in the following
way: the excess of precipitant, chloroplatinic acid H_{2}PtCl_{6},
which has the ion PtCl_{6}^{2−} in common with the precipitate, is
‹first removed› from the precipitate by thorough washing of the
precipitate with alcohol; subsequently, other impurities, ‹e.g.›
sulphates, soluble in water but not in alcohol, are washed out
with an aqueous solution of ammonium chloride[315] that has been
saturated with potassium chloroplatinate. The method gives good
results.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account