The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
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The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
That brings us to the second question, why aluminium hydroxide
should show this dual character, whereas, for instance, sodium and
magnesium hydroxides, which have similar structures, do not show
it. The best answer to this question is found when we consider the
properties of the elements and their derivatives in connection with
their position in the periodic or natural system of elements, which
shows the properties as (periodic) functions of the atomic weights.
In the second series of the elements,[355] omitting the zero group
element neon and taking the elements in the order of increasing
atomic weights, we have sodium (23), magnesium (24), aluminium (27),
silicon (28), phosphorus (31), sulphur (32), and chlorine (35.5). One
of the properties that are shown to be functions dependent on the
atomic weight, is the property under discussion, namely the tendency
of the (highest) hydroxides of the elements to ionize as bases or
acids, respectively. It is clear that the hydroxides of the elements
with the lowest atomic weights in the series, sodium and magnesium,
show the most pronounced tendency to ionize as bases; the hydroxides
of the elements with the highest atomic weights show the most
pronounced tendency to ionize as acids—perchloric acid, (HO)ClO_{3},
and sulphuric acid, (HO)_{2}SO_{2}, belong to the strongest acids. In
accordance with the underlying principle of the periodic system, the
change of [p173] properties, in going from one extreme to the other,
is a function of the increase in atomic weight and is not sudden but
‹gradual›. And so the basic function, the tendency to produce the
hydroxide-ion, is found to grow ‹weaker› as one goes from sodium to
magnesium and then to aluminium, hydroxide; and the acid function,
the tendency to produce the hydrogen-ion, grows markedly stronger,
as one goes from phosphoric to sulphuric and perchloric acids. It
is not surprising to find the two functions existing together, ‹but
in rather weak form, in the case of the intermediate hydroxides›,
notably in aluminium hydroxide and, to some degree, in silicic
acid, ‹the acid character beginning before the basic function has
ceased›. In accordance with this view, aluminium hydroxide is found
to be only a ‹weak›, slightly ionized base, and a ‹very weak›, even
less readily ionizable acid. In the case of silicic acid, which is
the next hydroxide one meets as one goes toward the acid end of the
series, the conditions are reversed. As the name indicates, it is
primarily an acid, but it is a very weak one, and a critical scrutiny
of its behavior shows it to have ‹very weak basic› functions, much
weaker than those of aluminium hydroxide. The question may, indeed,
be raised, whether either the basic or the acid properties really die
out altogether in the hydroxides, from one end of the series to the
other. In view of the small tendency toward sudden changes found in
nature, one might suspect traces of basic character to be preserved
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