The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
right through the series to the strongest acids, like perchloric
acid. As a matter of fact, later (see Chapter XV), we shall be
obliged to consider possible basic functions of the strongest oxygen
acids, such as nitric, perchloric, permanganic acids, and one of
their most important properties, their behavior as oxidizing agents,
will be found to be probably intimately associated with this remnant
of basic ionization. On the other hand, fused sodium hydroxide will
dissolve sodium with evolution of hydrogen, sodium oxide, Na—O—Na,
being formed; and it can readily be shown,[356] that in the fused
hydroxide there must be at least a few ions NaO^{−}, besides HO^{−},
H^{+}, O^{2−}, and Na^{+}. [p174]
The position of aluminium in the periodic system adequately
accounts, then, for the amphoteric character of its hydroxide.[357]
«Common Occurrence of Amphoteric Hydroxides.»—If we consider the
question of amphoteric behavior a little longer—its consequences are
used extensively in analytical work—we find, in the periodic system,
two other regular changes concerning acid and basic functions, only
one of which we shall discuss here.[358] While in a ‹series› of
elements the acid character of the hydroxides increases with the
atomic weight, in a family of elements the reverse relation holds.
From nitrogen to bismuth, in the nitrogen family of the sixth column
of the periodic system, the acid character of the hydroxides grows
steadily weaker, the basic character increases, and we find, again,
that the intermediate elements, notably arsenic and antimony, produce
hydroxides, which show markedly amphoteric character.
If, in the second series of the periodic group, one goes back from
aluminium to magnesium hydroxide, in accordance with the first
general principle laid down a much stronger base is found; and if one
then goes, in the magnesium family, to the hydroxide of the element
of next lower atomic weight, glucinum or beryllium, one again meets,
in accordance with the second principle laid down, a weaker basic
and more acidic hydroxide than magnesium hydroxide; in other words,
the basic and acid functions revert closely to those exhibited by
aluminium hydroxide. Glucinum hydroxide is a pronounced amphoteric
hydroxide and resembles aluminium hydroxide so closely that, in the
early history of chemistry, it was mistaken for the latter.
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