The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
If one goes from glucinum back to lithium, in the same series of the
periodic system, and from lithium to the element with the next lower
atomic weight in the same group, one comes to hydrogen, which forms
one of the most important and interesting of the [p175] amphoteric
hydroxides, water. The ionization of water, slight as it is, yields
hydrogen-ion and hydroxide-ion, the ions characteristic of acids and
of bases, and water is placed among the weakest of the acids (see
table, p. 104) as well as among the weakest of the bases (table, p.
106). We shall return to these relations, presently, and shall find
that the apparent weakness of water, as a base and as an acid, is
seemingly very largely due to the fact that water represents only an
extremely dilute solution (see p. 66) of the real hydroxide, HOH, or
hydrol, and consists very largely of a compound (H_{2}O)_{2}. H_{2}O,
or hydrol, is, perhaps, not very much weaker as an acid or as a base,
than is aluminium hydroxide.
Lower oxides of elements in the higher (acid-forming) groups show a
less pronounced acid-forming character than the higher oxides, and
a greater tendency to produce bases as well as acids, and are often
amphoteric. Chromium hydroxide is of this type.
In view of all these facts, and in view, also, of the fact that the
majority of the seventy-odd elements cannot lie at the ends of the
periodic system but are found in the middle, it is not surprising to
find that ‹pronounced amphoterism is shown by a large number of metal
hydroxides; it is, perhaps, the rule rather than the exception›. A
considerable number of the elements in the middle of the system are
rare elements and that is perhaps the chief reason why this relation
does not stand out more prominently in the consideration of the
common acids and bases.
«Amphoteric Character of Hydroxides Considered in Analysis.»—The
amphoteric character of hydroxides is frequently made use of in
analytical work in the separation and identification of various
elements and, when present, it must always be considered, in order
to escape possible error. The following hydroxides of the common
elements show ‹pronounced amphoteric› character: aluminium, chromic,
zinc, lead, stannous, antimonous hydroxides and arsenious, platinic,
auric, antimonic and stannic acids. Arsenic acid, ferric hydroxide
and silicic acid show exceedingly slight, but perceptible, amphoteric
character, sufficient to affect, to a certain degree, their
analytical behavior.[359] [p176]
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