The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
suitable for reading by the young student are specially designated.
The obvious demand is thereby made on the student to aim to remain
in touch with the growth of the science, after he has completed his
studies under the guidance of an instructor. Finally, to arouse
and develop the critical, questioning attitude of the professional
chemist, referred to above, the subject matter of the laboratory
work, given in Part III, is put very largely in the form of
questions, which demand not only careful observation on the part of
the student, but also a thoughtful interpretation of the observations
made.
In the experience of the author, although the majority of students
attending his lectures had already acquired some knowledge of
chemical and physical equilibrium, of the theories of solutions
and of ionization and of their applications, the more exhaustive
treatment of parts of these subjects and of related topics, to which
a course in qualitative analysis lends itself, has been of particular
benefit to them, bringing them into closer touch with the method of
detailed study of a chemical topic, than the broader, more varied
work of general chemistry courses usually does. Throughout the
theoretical treatment of the subject, the attempt is made to prepare
the student for a more general ‹quantitative› expression of chemical
relations. For this reason, chemical and physical equilibrium
constants are given and used, wherever it is possible. The author
is aware that these "constants" have, in part, only a temporary
standing; that more exact work will continually modify their
numerical values and, probably, limit the field for their ‹rigorous›
application. The latter facts can be impressed on the student and
still the invaluable principle be inculcated in his mind, that
chemistry is striving to express its relations, as far as possible,
in mathematical terms, exactly as its sister science, physics, has
long been doing. At the same time the treatment of physicochemical
topics has been kept within the bounds set by the subject matter, and
by the chemical maturity of the students addressed: it is elementary
in form, and quantitative relations are used, in the main, only to
elucidate qualitative facts. The rigorous development of the subjects
presented and their elaboration from a purely physicochemical
standpoint are left to advanced courses. It has been found that
this method interests the better class of students in seeking such
advanced courses.
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