The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution. — John Shaqi
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
the solvent in the solution, will be less than the solubility (‹c›)
at ‹A›, where the membrane is in contact with the pure solvent, and
water will pass into the solution at ‹B›, until the concentration of
the water in the membrane at ‹B› has fallen [p024] from (‹c›) to
(‹c′›). In such a membrane, as in every solution or gas, there must
be a tendency towards the establishing of uniform concentration by
diffusion from points of higher concentration to those of lower, and
the solvent will, therefore, ‹diffuse from points along the surface
A of the membrane to points along the surface B›; the surface ‹A›
will become ‹unsaturated› and will take up solvent from the pure
liquid bathing it, and the surface ‹B› will be kept continuously
supersaturated and will lose solvent continually to the solution.
Consequently, the solvent will pass continuously through the
membrane from the pure solvent to the solution. Equilibrium will be
reached, and the flow will cease, only ‹when the solution has become
infinitely dilute›, equal hydrostatic pressure obtaining on solution
and solvent, or ‹when the disturbing influence of the solute, which
dilutes the solvent in the solution, is exactly counterbalanced by an
external hydrostatic pressure, exerted on the solution›. When such a
pressure on the surface of the solution balances the force exerted
against the solvent by the solute we shall have equilibrium. It is
clear, then, that the ‹osmosis›, or passage of the solvent through
the membrane, is brought about by the unequal concentrations (or,
more exactly, the resulting ‹unequal partial pressures›) ‹of the
solvent itself. But this inequality is produced by the presence of
the solute, and it is a characteristic and significant fact, that
the effect of the latter, in dilute solutions, may be overcome by a
hydrostatic pressure, corresponding to the gas pressure which the
same number of molecules of a gas in the same volume at the same
temperature would exert against this hydrostatic pressure›.
[Illustration: FIG. 6.]
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