The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
Conversely, we frequently have occasion to oxidize ferrous salts to
the ferric condition, and among the most convenient reagents for the
purpose are chlorine and bromine water (‹exp.›). For instance, we
have 2 FeCl_{2} + Cl_{2} → 2 FeCl_{3}, or, considering the action
from the point of view of the theory of ionization,[514] 2 Fe^{2+} +
Cl_{2} → 2 Fe^{3+} + 2 Cl^{−}. In this case the oxidation of the
ferrous to the ferric ion consists in the assumption of an additional
positive charge; reduction of chlorine to the chloride-ion consists
in the assumption of negative charges by the chlorine atoms.
«Definitions of Oxidation and Reduction in Electric Terms.»—The
definitions must then be amplified and ‹oxidation be considered
to involve ultimately the assumption of positive, or the loss of
negative, electrical charges by ions or atoms, reduction to involve
ultimately the assumption of negative, or the loss of positive,
charges›. According to the electron theory of electricity a unit
negative charge is an electron, the unit positive charge, probably,
the charge left on an atom when it has lost an electron; and, thus,
oxidation may simply be defined, according to the electric theory of
oxidation and reduction, as consisting, fundamentally, in the ‹loss
of electrons by atoms or ions›, reduction as consisting in a ‹gain
of electrons›. For instance, when hydrogen sulphide reduces a ferric
salt, 2 Fe^{3+} + S^{2−} → 2 Fe^{2+} + S, ‹the sulphide ions transfer
their electrons to the ferric ions›.
«Oxidations and Reductions by Electric Currents.»—All of the
oxidation and reduction reactions which have been discussed may, in
fact, be effected by the use of an ‹electric current› in the place of
chemical agents. Ferrous salts, for instance, are ‹oxidized›, at the
positive pole, by the current to ferric salts:[515]
Fe^{2+} + ⊕ → Fe^{3+}, or Fe^{2+} − ε^{−} → Fe^{3+}.
Ferric salts are ‹reduced›, at the negative pole, to ferrous salts:
Fe^{3+} + ⊖ → Fe^{2+}, or Fe^{3+} + ε^{−} → Fe^{2+}.
[p253]
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