The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
EXP.—A solution of ferrous chloride, freshly prepared from iron
wire, or a freshly prepared solution of ferrous-ammonium sulphate,
is placed in a very small beaker; a solution of ferric chloride,
acidulated with hydrochloric acid to prevent subsequent complete
reduction of the ferric-ion to iron, is brought into a similar
beaker. A small amount (5 c.c.) of each solution is tested, the
former with potassium thiocyanate and the latter with ferricyanide
solution, to show the absence of perceptible quantities of ferric
and ferrous ions in them, respectively. Platinum electrodes,
consisting best of cylinders of platinum gauze, are introduced into
the solutions, the solutions are connected by means of a "salt
bridge" (a U-tube filled with a solution of sodium chloride and
closed at both ends by plugs of filter paper), and a current of 0.2
ampere is passed through the system, the positive current entering
the solution containing the ferrous salt. After the current has
been allowed to pass for a minute or two, 5 c.c. is withdrawn, by a
pipette, from the meshes of the positive electrode and tested with
thiocyanate, and 5 c.c., withdrawn in the same way from the negative
electrode, is tested with potassium ferricyanide.
«Production of Electric Currents by Means of Oxidation and Reduction
Reactions.»—Not only may all the oxidations and reductions which we
have discussed be accomplished with the aid of the electric current,
but ‹vice versa›, an electric current may readily be produced by a
proper arrangement of the components of any one of these reactions.
Care need only be taken to have the simultaneous loss and gain of
electrons, characteristic of all oxidation and reduction reactions,
occur in separate localities, which must be connected, however,
in such a way as to make the transfer of electrons, a flow of
electricity, possible.
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