The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
EXP. For instance, some ferric chloride and sodium chloride solution
may be put into a small beaker, some sodium chloride solution
into a second beaker of the same size, and the two solutions
connected, first by means of a "salt-bridge," and then by means of
two platinum electrodes dipping into the solutions and connected
with the terminals of a sensitive voltmeter.[516] If [p254] all
of the connections are made, the introduction of the "salt-bridge"
being left to the last, a momentary slight motion of the needle is
observed, when the bridge is introduced. The needle then falls back
to the zero point (see p. 276). If now some hydrogen sulphide water
is poured into the beaker containing sodium chloride, a decided, and
continuing, deflection of the needle of the voltmeter is immediately
observed, showing the passage of an electric current, and it is
in the direction anticipated by the consideration of the reaction
equation: 2 Fe^{3+} + S^{2−} → 2 Fe^{2+} + S ↓. The positive current
passes into the voltmeter from the ferric chloride solution, where
ferric ions are giving up their charges; the negative current enters
the voltmeter from the solution containing the hydrogen sulphide,
where sulphide ions are being discharged. The "salt-bridge" is
necessary to complete the electrical circuit and prevent any local
accumulation of positive or negative electricity (polarization). For
instance, as the ferric ions are discharged, an excess of chloride
ions would remain in the beaker, rendering the solution negative and
preventing the flow of electricity from the electrode, if negative
ions did not move off, through the "salt-bridge," into the beaker
containing hydrogen sulphide and, simultaneously, positive ions
migrate into the beaker containing the ferric salt. Similarly,
the accumulation of positive electricity in the hydrogen sulphide
solution, on account of the hydrogen ions left free by the discharge
of sulphide ions, is prevented by the flow of positive ions (sodium
and hydrogen) through the U-tube into the beaker containing the
ferric chloride and the flow of negative (chloride) ions into the
hydrogen sulphide solution. Thus a current of electricity passes
through the whole circuit.
It is thus possible to reduce ferric chloride in one vessel by
hydrogen sulphide poured into another vessel,[517] and an electric
current may be obtained from the simultaneous discharge of the
sulphide and ferric ions in the action.
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