The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution. — John Shaqi
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
one time advanced by some chemists, must be considered as altogether
untenable.
A third explanation of the "abnormally" low molecular weights,
which certain substances in aqueous solutions possess, is, that
the molecules of these compounds are ‹capable of dissociation into
smaller molecules of unlike composition›, somewhat like ammonium
chloride when it is heated, and that the substances in question
are dissociated more or less considerably in this fashion in the
solutions under consideration. Hydrogen chloride, for instance,
besides existing as such (as HCl), in aqueous solutions, might
be capable of dissociating, and actually be dissociated, to a
considerable degree into molecules containing either only hydrogen
or only chlorine (HCl ⇄ H + Cl); the ‹average› of the weights of
the molecules in a mixture of molecules, HCl, H, and Cl, would be
‹less› than 36.5, and, according to the proportion of dissociated and
undissociated molecules of hydrogen chloride, the average would lie
between the limits 36.5 and (1 + 35.5) / 2, or 18.25. Such an [p040]
explanation,[61] made with ‹certain additions and restrictions›, was
advanced in 1885 by Arrhenius, a Swedish chemist and physicist, when
he learned of the exceptional behavior of these solutions, as noted
by van 't Hoff. Although at first this interpretation occasioned
considerable criticism, it has maintained itself successfully for
twenty years, on the basis of a wide range of accumulated facts, and
it has been of remarkable value and benefit in the development of all
branches of chemistry and the allied sciences.
«The Theory of Ionization.»—Arrhenius[2] made the simple observation
that all those solutions, in which the dissolved compounds seem to
have abnormally low molecular weights, are solutions through which an
‹electric current› may be readily passed, they are ‹electrolytes›,
whereas the solutions which give normal results (see, for instance,
the table on p. 37) do not allow the ready passage of a current, they
are ‹nonelectrolytes›.
EXP. The fundamental difference between the two classes of solutions
may readily be demonstrated. To water contained in an electrolytic
cell, which is connected with a lighting circuit and with an
electric lamp, first some alcohol, and later a small quantity of
hydrochloric acid are added. The lamp is seen to glow, instantly,
when the acid is added.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account