The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
We thus find that the most exact work on molecular weight
determinations in ‹dilute› aqueous solutions agrees excellently,
as does the conductivity of such solutions, with the demands of
the theory of ionization, a fact which is particularly impressive
because osmotic pressure and electrical conductivity are in no wise
fundamentally related phenomena, and yet each, as a measure of
ionization or electrolytic dissociation, leads independently to the
same conclusion.[120]
«The Chemical Composition of the Ions of Electrolytes.»—Accepting the
theory of Arrhenius, we may now inquire more closely than heretofore,
first, what compounds are subject to electrolytic dissociation, and
then, what the chemical composition of their ions is and how it is
determined.
The compounds which are dissociated into ions, by solvents which
cause ionization (p. 62), comprise the ‹salts›, the ‹acids› and the
‹bases›; chemists are, in fact, more inclined now to invert the
statement and say that those substances which have long been known
as salts, acids and bases, owe the essential characteristics, which
led to their classification, to the fact that they are ionizable (see
pp. 72–82). The composition of the ions, formed from the simpler
of these compounds,[121] may be expressed by saying that the metal
component or metal-like component (hydrogen, ammonium) forms the
positive ion (cation, metal ion) and all the rest of the [p070]
molecule forms the negative ion (anion, acid ion[122]). Thus,
sodium chloride, nitrate, sulphate, phosphate yield the sodium-ion,
Na^{+}, and the chloride (Cl^{−}), nitrate (NO_{3}^{−}), sulphate
(SO_{4}^{2−}), or phosphate (PO_{4}^{3−}) ions; cupric nitrate
Cu(NO_{3})_{2} dissociates into the cupric ion (Cu^{2+}) and the
nitrate ion, calcium sulphate CaSO_{4} into the calcium-ion (Ca^{2+})
and the sulphate-ion, aluminium sulphate Al_{2}(SO_{4})_{3} into the
aluminium-ion (Al^{3+}) and the sulphate-ion.
But the question arises, as to how we know that the salts mentioned
produce ions of the given composition; why, for instance, should
sodium nitrate be considered to dissociate into sodium, Na^{+}, and
nitrate ions, NO_{3}^{−}, the nitrogen atom carrying all of the
oxygen atoms with it in the negative ion?
[Illustration: FIG. 13.]
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