The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
of some chloride ions out of ‹N› into the space ‹C›, and, at the same
time, a migration of the positive ions of space ‹C› into the division
‹N›. On examining the solution in ‹N›, we now find sodium chloride,
with unchanged hydrochloric acid, exactly what we should expect from
the migration of the ion Na^{+} toward the negative electrode.[124]
If the positive ion were, say, [p072] NaO^{+}, we should expect to
obtain either some of the hypochlorite NaOCl (NaO^{+} + Cl^{−}), or,
at least, an evolution of oxygen in this place, since sodium chloride
is formed. As a matter of experiment, no oxygen is evolved here, and
no trace of hypochlorite is found in ‹N› round the negative pole,
although the tests for hypochlorites are extremely sensitive.
Comparatively simple methods, in principle of the nature outlined,
enable us, then, to ‹determine experimentally› the composition of
the ions into which ionizable compounds, salts, acids and bases,
dissociate. Whenever any doubt may exist about the composition of the
ions of a given electrolyte, this device may be employed to settle
the matter, and there will presently be occasion to employ the U-tube
for such a purpose.
‹Ionization and Chemical Activity.›—The fact that the theory of
ionization gives us adequate explanations of the conductivity shown
by dissolved electrolytes and of their abnormally high osmotic
pressures, would have been in itself of interest to chemists; but,
if its applications were limited to these phenomena, we should not
be considering it in connection with qualitative chemical analysis,
nor would the theory, presumably, have greatly affected the
development of chemistry, as it has done. It is the fact that the
electrolytic dissociation of an electrolyte into its ions involves
‹chemical› changes of the most profound nature, and most intimately
affects ‹chemical› reactivity, that has made it play, in the last
two decades, such a leading rôle in the development of chemistry,
and that makes it necessary to include its consequences in the
consideration of analytical problems, if one would understand, as
far as present knowledge permits, the reactions involved in chemical
analysis.
Hydrogen chloride, as a perfectly dry gas, is a non-conductor of
electricity and, at the same time, it is found to be chemically
‹inactive›—it does not combine, for instance, with dry ammonia[125]
or act upon dry calcium carbonate[126] or on dry litmus. Hydrogen
chloride, subjected to great pressure at a low temperature, is
liquefied. The liquid is also a very poor conductor of [p073]
electricity[127] and does not show the chemical activity of
ordinary, aqueous hydrochloric acid; it does not combine with calcium
oxide or attack marble, zinc, iron or even magnesium.[127]
A solution of hydrogen chloride in a poorly ionizing medium,
like benzene or toluene, is an extremely poor conductor. There
is an extremely small conductivity indicating only a trace of
ionization.[128]
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