The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
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The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
EXP. A solution of hydrogen chloride, prepared by passing the dried
gas into benzene or toluene (thiophene-free benzene will not become
discolored), and kept anhydrous by means of fused calcium chloride,
is tested for its conductivity, by dipping into it electrodes
connected with a lighting circuit and a galvanometer.
Such a solution behaves chemically, also, quite differently from
the aqueous solutions of hydrogen chloride with which we are
familiar: dry steel nails,[129] dropped into it, will remain almost
unchanged—there is no marked evolution of hydrogen (‹exp.›).
Perfectly dried marble, added to it, will not give rise to the
evolution of carbon dioxide[129] (‹exp.›). We find thus, in all the
cases discussed—the nonconducting dry gas, the anhydrous liquefied
hydrogen chloride and the anhydrous benzene solution—an absence of
ionization,[130] as indicated by the lack of conductivity, and, along
with this, a lack of the familiar action of hydrochloric acid as an
acid. If we dissolve the gas in water, we obtain a well-conducting
solution (‹exp.›), in which, according to molecular weight
determinations, the [p074] hydrogen chloride is more or less largely
ionized, and this same solution has all the well-known chemical
properties of hydrochloric acid—it evolves hydrogen liberally when
given an opportunity to act upon zinc or iron (‹exp.›), it evolves
carbon dioxide copiously when marble is brought into contact with it
(‹exp.›). In such an aqueous solution we have both the ions of the
acid and the more or less non-ionized hydrogen chloride, the action
(HCl ⇄ H^{+} + Cl^{−}) being reversible.
Now, since in those cases in which we have admittedly only
non-ionized hydrogen chloride, there is no vigorous chemical action,
we are bound to conclude that, in the aqueous solution where we have
both the non-ionized and the ionized substance, it must be the new
components, the ions of the acid, which give this solution its new
qualities, the well-known properties of a pronounced acid.[131] This
conclusion, that the acid properties of hydrogen chloride in aqueous
solution are due to the ionized hydrogen chloride, rather than to the
hydrogen chloride itself, is one of fundamental importance.
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