The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
«Influence of Light and Heat.»—It is apparent that heat, a form
of energy, contributes to the dissociation of ionogens, and it is
natural that we should consider other forms of energy, ‹e.g.› light,
to have the same power. One may speculate about the possibility of
light inducing chemical action (‹e.g.› in starting the combination
of hydrogen and chlorine, or in photography) by its ionizing power,
and about the possibility that rapid combination of oxygen and
hydrogen follows the application of a flame to the mixture, as the
result of increased ionization of the components at the elevated
temperature of the flame and of the burning gases. The experimental
evidence shows that, in some actions of this nature, ionization
is an important factor, while in other instances it appears to be
negligible.[135] [p077]
«Conclusions.»—It appears that we must accept the conclusion, that
the ‹reactions of salts›, ‹acids› and ‹bases› (ionogens) ‹in aqueous
solution› (the so-called "salt reactions") ‹are the reactions of the
ions and not of the non-ionized molecules.› This conclusion is of
the greatest and most practical importance in our science. It is the
natural inference from the results of the qualitative experiments
described in the three preceding sections. Its final adoption,
however, is based on the existence of a great mass of ‹quantitative
evidence›, and to the consideration of some of this we now turn.
«Quantitative Relations.»—If the active components in aqueous
solutions of acids, bases and salts are the ions, rather than the
undissociated compounds, then quantitative data supporting such a
conclusion should be found. Such quantitative confirmation, from the
point of view of chemical activity, is not lacking. Only a small part
of the data can be considered here.
Conductivity measurements, and the lowering of freezing-points
and the elevation of boiling-points, show that there are very
decided differences ‹in the degrees of ionization of different
acids and bases› in solutions of equivalent concentration. For
instance, potassium hydroxide is somewhat more ionized than is
barium hydroxide, and decidedly more so than ammonium hydroxide, a
fact that can readily be demonstrated by the conductivities of the
solutions[136]:
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