The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
EXP. Equivalent solutions (1 / 10 normal) of the three bases
are introduced into three vertical tubes, containing electrodes
connected, in parallel, with a lighting circuit and with small
electric lamps. When the two electrodes in each of the three tubes
are at equal distances from each other, the lamp connected with the
potassium hydroxide solution glows most brightly, that connected
with the barium hydroxide solution a little less brightly, and the
lamp connected with the ammonium hydroxide solution does not glow
at all—not enough current is carried through the ammonium hydroxide
solution to heat the filament in the corresponding lamp sufficiently
to make it red. Now, the current, for a given fall of potential, is
proportional to the conductivity of a solution (p. 48) and, in the
equivalent solutions[137] the conductivity depends on the proportion
of charged particles (the degree of ionization) of the base. It is
clear then, that ammonium hydroxide is very much less ionized than
are the two other bases. [p078]
The resistance in a tube may be reduced, and the conductivity
increased, by reducing the distance through which the current must
be carried, ‹i.e.› by bringing the electrodes closer together.
In the solution of barium hydroxide, we find that we must reduce
the distance between the electrodes to about five-sixths the
corresponding distance in the potassium hydroxide solution before
we obtain, approximately, as bright a lamp from the current passing
through it, and in the case of ammonium hydroxide, we must bring the
electrodes so close together that they almost touch, the distance
being only one or two hundredths of the distance between the
electrodes in the potassium hydroxide solution.
For the degrees of ionization of the three bases we have,
approximately, the relation α_{K} : α_{Ba} : α_{NH_{4}}::
‹d›_{K} : ‹d›_{Ba} : ‹d›_{NH_{4}}, if we indicate by ‹d›_{K},
‹d›_{Ba}, ‹d›_{NH_{4}} the distances between the electrodes in the
three solutions when the lamps are of uniform brightness, ‹i.e.›
when the same quantity of current passes through each solution. In
this deduction, the conductivities of the bases at infinite dilution
(Λ_{∞}) are taken to be the same, which is roughly true.
The experiment gives us a rough measure of the relative
conductivities and the relative degrees of ionization of the three
bases. It shows that potassium hydroxide is somewhat more ionized
than is barium hydroxide, in equivalent solution, and decidedly more
than is ammonium hydroxide.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account