The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
EXP. A rough idea of the difference in the chemical actions of the
two bases may be obtained by observing their effects on the ester,
methyl acetate, which is decomposed into an acetate and methyl
alcohol rather rapidly. To 50 c.c. of (CO_{2} free) water containing
some phenolphthaleïn, 10 c.c. of 0.1 molar potassium hydroxide
is added; a similar mixture with 10 c.c. of 0.1 molar ammonium
hydroxide solution is prepared. To each of the solutions, 2 c.c.
(an excess) of methyl acetate is added (to the ammonium hydroxide
solution first), and the mixtures are shaken for a moment. At room
temperature, the mixture containing potassium hydroxide will become
pale pink in a few minutes, and colorless soon thereafter, while the
mixture [p081] containing ammonium hydroxide will still be deep red
at the end of 45 minutes.[141]
In the following tables are summarized some of the results
which have been obtained in comparing the ‹activity of bases›,
in saponifying methyl acetate, and ‹the concentrations of the
hydroxide-ion›, in the solutions of the bases, as determined by
conductivity measurements. The comparisons are made by representing
the activity of the hydroxide-ion in a solution of lithium hydroxide
by 100 and by expressing the ratio of the activity of a given base
to that of the lithium hydroxide in percentages of the activity of
the latter. All the bases were used in 0.025 molar concentration,
and their degrees of ionization are given in the last column of the
table.
CHEMICAL ACTIVITY OF BASES AND THEIR IONIZATION[A]
Relative
Base. Activity. Concentration
of HO^{−}.
Lithium hydroxide 100 97
Potassium hydroxide 98 97
Sodium hydroxide 98 97
Ammonium hydroxide 2 2.5
Ethyl ammonium hydroxide 12 16.
TABLE NOTE:
A. Whetham, ‹Theory of Solutions›, p. 338 (1902). (‹Cf.›
Walker, ‹Introduction to Physical Chemistry›, p. 277 (1899).)
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