The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.Stieglitz, Julius
Science
The Elements of Qualitative Chemical Analysis, vol. 1, parts 1 and 2.: With Special Consideration of the Application of the Laws of Equilibrium and of the Modern Theories of Solution.
Stieglitz, Julius
Chemistry, Analytic -- Qualitative
An ester is decomposed also ‹under the influence of acids›,
in aqueous solution, into an organic acid and an alcohol,
and cane sugar is similarly decomposed into glucose and
fructose (grape sugar and fruit sugar): C_{12}H_{22}O_{11} +
H_{2}O → C_{6}H_{12}O_{6} + C_{6}H_{12}O_{6}. Both actions are
found to be caused by the influence of the ‹hydrogen ions› of
the acids used and to proceed, at a given temperature, ‹with a
velocity proportional to the concentration of the hydrogen ions›.
Now, in 0.1 molar solution, acetic acid is very little ionized
(1.3%), as compared with hydrochloric acid (91%), the degrees
of ionization being determined by conductivity measurements (p.
50); the relation may easily be demonstrated with the aid of the
conductivity apparatus used to show the difference in ionization
between potassium hydroxide and ammonium hydroxide. In the presence
of 0.1 molar hydrochloric acid, the decomposition of cane sugar
actually proceeds at 79 times the rate that it does in the presence
of 0.1 molar acetic acid. The ratio of the concentrations of the
hydrogen-ion in the two [p082] solutions is, in fact, 70 : 1.
There is, therefore, close agreement[142] between the ‹relative
chemical activity› of the two acids and the relation demanded, if
we assume, on the basis of the theory of ionization (p. 77), ‹that
the chemically active components of the acids are their ions and
particularly their hydrogen ions›.
In the following table, the relative activities of acids, in
accelerating the decomposition of methyl acetate by water,
are contrasted, in a similar fashion, with their relative
conductivities. The conductivities of acids depend to such an extent
on the concentration of hydrogen-ion, which moves five times, or
more, faster than the anions and carries therefore the greater part
of the current, that the conductivities of acids, in equivalent
concentrations, may be considered an approximate measure of their
relative degrees of ionization and ‹of the concentrations of
hydrogen-ion›. For the purpose of comparison the activity and the
conductivity of molar hydrochloric acid are both represented by 100.
All the acids were used in normal solutions.
CHEMICAL ACTIVITY OF ACIDS AND THEIR IONIZATION.[A]
Acid. Activity. Conductivity.
Hydrochloric acid 100 100
Nitric acid 92 100
Sulphuric acid 74 65
Acetic acid 0.3 0.4
Formic acid 1.3 1.7
Chloracetic acid 4.3 4.9
Tartaric acid 2.3 2.3
TABLE NOTE:
A. Whetham, ‹Theory of Solutions›, p. 338.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account